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关键词:       仅模糊查询
CAS: 19692-45-6
分子式: C11H15Cl
分子量: 182.69
沸点: 101-105 °C7 mm Hg(lit.)
中文名称: 
对叔丁基氯化苄
对叔丁基氯苄
4-叔丁基氯化苄
对叔丁基苄基氯
4-叔-丁基苯甲基氯
英文名称: 
p-tert-Butylbenzyl chloride
Benzene,1-(chloromethyl)-4-(1,1-dimethylethyl)-
4-(tert-Butyl)benzyl chloride
1-(chloromethyl)-4-(1,1-dimethylethyl)-Benzene
1-(chloromethyl)-4-(1,1-dimethylethyl)-benzen
1-Chloromethyl-4-tert-butylbenzene
4-tert-Butyl-alpha-chlorotoluene
4-tert-butyl benzyl chloride
4-tert-Butylbenzyl chloride
性质描述: 沸点101-105℃(9.33kPa),相对密度0.945,折射率1.5218,闪点94℃。
生产方法: 有3种合成方法。1.叔丁醇法 由叔丁基苯经氯甲基化而得。将叔丁基苯、盐酸、多聚甲醛、氯化锌、冰乙酸投入反应锅,于65℃滴加三氯化磷,加毕,在65-70℃搅拌7h。然后冷至30℃,取上层苄氯粗品,除氯化氢、脱水过滤,减压蒸馏,收集124-132℃(3.33kPa)馏分,即为对叔丁基氯苄。2.叔丁苯氯甲基化法3.对叔丁基甲苯氯化法
用途: 有机合成的重要中间体,主要用于医药、农药及香料方面。抗过敏药物安其敏、氯苯丁嗪的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
B818662MACKLIN4-叔丁基苄氯≥96%29元/5g;   30元/25g;   61元/100g;   209元/500g;   943元/2.5kg;   咨询
储存:室温
状态:无色液体
折射率:n20/D 1.521(lit.)
B2235TCI4-tert-Butylbenzyl Chloride>89.0%(GC)150元/5G;   590元/25G;   咨询

基本信息

纯度/分析方法>89.0%(GC)
分子式/分子量C11H15Cl = 182.69
外观与形状(20℃)液体
Reaxys-RN471673
PubChem物质ID87565089
MDL编号MFCD00000918

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 89.0 %

物性(参考值)

闪点94 ℃
比重1.01
折射率1.52

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN1760
类别8
包装类别 III
监管条件代码(*)
198005J&K4-tert-Butylbenzyl Chloride96%397元/5G;   1465元/25G;   咨询

基本信息

分子式C11H15Cl
分子量182.69
沸点101-105
闪点94
密度0.945
折光率(n20D)1.5210
MDL编码MFCD00000918
Beilstein471673
EINECS 编号243-228-8

安全信息

图形或危害标志
提示语Danger
危险说明H314
H335
防范说明P261
P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK3
TSCA
A11856Alfa Aesar4-tert-Butylbenzyl Chloride99%970元/5g;   3090元/25g;   咨询

应用
4-tert-Butylbenzyl chloride has been used to control molecular weight and prevent microgel formation during polymerization reaction.

备注
Store in cool, dry conditions in well sealed container. Store away from oxidizing agent. Store away from strong bases.

基本信息

MDL
MFCD00000918

EINECS
243-228-8

分子式
C11H15Cl

分子量
182.70

沸点
101-104°/7mm

闪点
94° (202°F)

密度
0.945

折射率
1.5220

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Slightly soluble in water.

Beilstein
471673

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C34549Alfa Aesar4-(tert-Butyl)benzylchloride97%800元/5g;   2983元/25g;   咨询

基本信息

Ref#
34549

MDL
918

分子式
C11 H15 Cl

分子量
182.69

闪点
94

密度
0.94

安全信息

危险等级
8

包装组
II

191531Sigma-Aldrich4-tert-Butylbenzyl chloride99%343.06元/5 G;   咨询

产品说明

应用

4-tert-Butylbenzyl chloride has been used to control molecular weight and prevent microgel formation during polymerization reaction.

包装

5 g in glass bottle

基本信息

线性分子式(CH3)3CC6H4CH2Cl
分子量182.69
Beilstein471673
EC 号243-228-8
MDL编号MFCD00000918
PubChem化学物质编号24851492
NACRESNA.22

产品性质

质量水平100
测定99%
折射率n20/D 1.521 (lit.)
bp101-105 ℃/7 mmHg (lit.)
密度0.945 g/mL at 25 ℃ (lit.)
SMILES stringCC(C)(C)c1ccc(CCl)cc1
InChI1S/C11H15Cl/c1-11(2,3)10-6-4-9(8-12)5-7-10/h4-7H,8H2,1-3H3
InChI keyWAXIFMGAKWIFDQ-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H314 - H335
预防措施声明P261 - P280 - P305 + P351 + P338 - P310
危险分类Eye Irrit. 2 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
209897Fluorochem1-(tert-Butyl)-4-(chloromethyl)benzene95%352元/5g;   660元/10g;   1276元/25g;   咨询

基本信息

CAS Number19692-45-6
MDL NumberMFCD00000918
Boiling Point101-105℃
Density0.945

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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