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CAS: 1897-52-5
分子式: C7H3F2N
分子量: 139.11
沸点: 197-198℃
熔点: 30-30℃
中文名称: 
2,6-二氟苯甲腈
2,6-二氟苯腈
英文名称: 
2,6-Difluorobenzonitrile
2,6-difluoro-benzonitril
2,6-Difluoro-benzonitrile
2,6-difluorophenylcyanide
性质描述: 97%工业品的熔点30-32℃,沸点197-198℃,闪点80℃。相对密度1.246,折光率(nD20)1.4875。
生产方法: 2,6-二氯苯腈与无水氟化钾在非质子性极性溶剂中进行高温氟化反应可制得2,6-二氟苯腈。生产1t2,6-二氟苯腈约需消耗1.2t2,6-二氯苯腈。
用途: 2,6-二氟苯腈为新型农药中间体,主要用于生产高效、低毒、广谱的含氟苯甲酰脲类杀虫剂、除草剂中间体2,6-二氟苯甲酰胺。在医药方面也有所应用。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807365MACKLIN2,6-二氟苯腈98%30元/5g;   34元/25g;   86元/100g;   312元/500g;   展开
储存:室温
状态:无色到黄色液体或固体
折射率:n20/D 1.4875(lit.)
D1650TCI2,6-Difluorobenzonitrile>99.0%(GC)390元/25G;   1075元/100G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C7H3F2N = 139.10
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN2045292
PubChem物质ID87568127
SDBS (AIST Spectral DB)4670
MDL编号MFCD00001778

技术规格

AppearanceWhite or Colorless to Light yellow powder to lump to clear liquid
Purity(GC)min. 99.0 %

物性(参考值)

熔点28 ℃
水溶性不溶

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

运输信息

UN编号UN3439
类别6.1
包装类别 III
监管条件代码(*)
326666J&K2,6-Difluorobenzonitrile99%124元/10G;   496元/50G;   展开

基本信息

分子式C7H3F2N
分子量139.10
熔点25-28
沸点197-198
闪点90
密度1.246
折光率(n20D)1.4875
MDL编码MFCD00001778
Beilstein2045292
EINECS 编号217-589-7

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H315
H319
H332
H335
防范说明P261
P280
P305+P351+P338
WGK3
TSCA
A10454Alfa Aesar2,6-Difluorobenzonitrile98%546元/10g;   2189元/50g;   8734元/250g;   展开

基本信息

MDL
MFCD00001778

EINECS
217-589-7

分子式
C7H3F2N

分子量
139.11

熔点
28-32°

沸点
197-198°

闪点
80°(176°F)

密度
1.246

折射率
1.4875

形态
Solid

Beilstein
2045292

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

186783Sigma-Aldrich2,6-Difluorobenzonitrile97%947.74元/50 G;   展开

产品说明

应用

2,6-Difluorobenzonitrile was used in the synthesis of:

  • poly(cyanoaryl ethers) via silyl-method
  • 2-dimethylamino-6-fluorobenzamide
  • phenolphthalein-modified polyarylene ether nitrile copolymers

包装

50 g in glass bottle

基本信息

线性分子式F2C6H3CN
分子量139.10
Beilstein2045292
EC 号217-589-7
MDL编号MFCD00001778
PubChem化学物质编号24851242
NACRESNA.22

产品性质

质量水平200
测定97%
折射率n20/D 1.4875 (lit.)
bp197-198 ℃
mp25-28 ℃ (lit.)
密度1.246 g/mL at 25 ℃ (lit.)
SMILES stringFc1cccc(F)c1C#N
InChI1S/C7H3F2N/c8-6-2-1-3-7(9)5(6)4-10/h1-3H
InChI keyBNBRIFIJRKJGEI-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 + H312 + H332 - H315 - H319 - H335
预防措施声明P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
001958Fluorochem2,6-Difluorobenzonitrile99%660元/100g;   1980元/500g;   展开

基本信息

CAS Number1897-52-5
MDL NumberMFCD00001778
Melting Point30-32℃
Density1.246

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
防范说明 P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to local regulations.
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