[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 185449-80-3
关键词:       仅模糊查询
CAS: 185449-80-3
分子式: C22H18NO2P
分子量: 359.4
熔点: 208-210°C
中文名称: 
(s)-(+)-(3,5-二氧-4-磷-环庚并[2,1-a;3,4- a′]二萘-4-基)二甲胺
(s)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine
(s)-磷酸苯丙胺
英文名称: 
(s)-monophos
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S853908MACKLIN(11bS)​-N,​N-​二甲基-联萘并[2,​1-​d:1',​2'-​f]​[1,​3,​2]二氧膦杂-​4-​胺≥98%,≥99% e.e.67元/1g;   200元/5g;   979元/25g;   展开
储存:室温,干燥
状态:白色-非常淡黄色晶体-粉末
D4993TCI(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine>98.0%(T)(HPLC)390元/1G;   1250元/5G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C22H18NO2P = 359.36
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN17845250
PubChem物质ID354334569
MDL编号MFCD03426988

技术规格

Purity(HPLC)min. 98.0 area%
Optical purity(LC)min. 98.0 ee%
Purity(Nonaqueous Titration)min. 98.0 %
Specific rotation [a]20/D+560 to +600 deg(C=0.3,CHCL3)

物性(参考值)

熔点227 ℃
比旋光度 [α]D583° (C=0.3,CHCl3)
15-1233Strem(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylaminemin. 97%334元/250mg;   1002元/1g;   展开

Technical Notes:

1.See 15-1232

2.Asymmetric hydrogenation of ketones and ß-keto esters.3.

3.L ight-induced, enantioselective hydrogenation.

References:

1.Org. L ett., 2004, 6, 4105.

2., Angew. Chem. Int. Ed., 2004, 43, 5066.

3.J. Org. Chem., 2005, 70, 943.

4. Organometallics, 2011, 3o, 3880.

Y10427Alfa Aesar(S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphep370元/1g;   1155元/5g;   4006元/25g;   展开

基本信息

分子量
359.36

668192Sigma-Aldrich(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine97%333.78元/250 MG;   473.26元/1 G;   展开

产品说明

应用

DSM MonoPhos Family of Highly Efficient Privileged Ligands

包装

250 mg in glass insert
1, 5 g in glass bottle

法律信息

经 DSM 授权销售,仅供研究使用。
MonoPhos is a registered trademark of DSM IP Assets B.V.

基本信息

经验(实验)分子式C22H18NO2P
分子量359.36
MDL编号MFCD03426988
PubChem化学物质编号24884967
NACRESNA.22

产品性质

质量水平100
测定97%
mp190 ℃ (dec.)
InChI1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3
InChI keyQCHAVHXSBZARBO-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
219451Fluorochem(S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine95%440元/250mg;   682元/1g;   1914元/5g;   3564元/10g;   展开

基本信息

CAS Number185449-80-3
MDL NumberMFCD03426988
Melting Point190℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H413: May cause long lasting harmful effects to aquatic life.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9