| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| S853908 | MACKLIN | (11bS)-N,N-二甲基-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺 | ≥98%,≥99% e.e. | 67元/1g; 200元/5g; 979元/25g; | 展开 |
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| D4993 | TCI | (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine | >98.0%(T)(HPLC) | 390元/1G; 1250元/5G; | 展开 |
基本信息 | 纯度/分析方法 | >98.0%(T)(HPLC) | | 分子式/分子量 | C22H18NO2P = 359.36 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 17845250 | | PubChem物质ID | 354334569 | | MDL编号 | MFCD03426988 |
技术规格 | Purity(HPLC) | min. 98.0 area% | | Optical purity(LC) | min. 98.0 ee% | | Purity(Nonaqueous Titration) | min. 98.0 % | | Specific rotation [a]20/D | +560 to +600 deg(C=0.3,CHCL3) |
物性(参考值) | 熔点 | 227 ℃ | | 比旋光度 [α]D | 583° (C=0.3,CHCl3) |
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| 15-1233 | Strem | (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine | min. 97% | 334元/250mg; 1002元/1g; | 展开 |
Technical Notes: 1.See 15-1232 2.Asymmetric hydrogenation of ketones and ß-keto esters.3. 3.L ight-induced, enantioselective hydrogenation. References: 1.Org. L ett., 2004, 6, 4105. 2., Angew. Chem. Int. Ed., 2004, 43, 5066. 3.J. Org. Chem., 2005, 70, 943. 4. Organometallics, 2011, 3o, 3880. |
| Y10427 | Alfa Aesar | (S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphep | | 370元/1g; 1155元/5g; 4006元/25g; | 展开 |
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| 668192 | Sigma-Aldrich | (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine | 97% | 333.78元/250 MG; 473.26元/1 G; | 展开 |
产品说明 应用 DSM MonoPhos Family of Highly Efficient Privileged Ligands 包装 250 mg in glass insert 1, 5 g in glass bottle 法律信息 经 DSM 授权销售,仅供研究使用。 MonoPhos is a registered trademark of DSM IP Assets B.V. 基本信息 | 经验(实验)分子式 | C22H18NO2P | | 分子量 | 359.36 | | MDL编号 | MFCD03426988 | | PubChem化学物质编号 | 24884967 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | mp | 190 ℃ (dec.) | | InChI | 1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3 | | InChI key | QCHAVHXSBZARBO-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable |
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| 219451 | Fluorochem | (S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | 95% | 440元/250mg; 682元/1g; 1914元/5g; 3564元/10g; | 展开 |
基本信息 | CAS Number | 185449-80-3 | | MDL Number | MFCD03426988 | | Melting Point | 190℃ |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H413: May cause long lasting harmful effects to aquatic life.
| | 防范说明 | P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.
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