CAS 185346-09-2; 2,6-双[(3as,8ar)-3a,8a-二氢-8h-茚并[1,2-d]噁唑啉-2-基]吡啶; 2,6-bis[(3as,8ar)-3a,8a-dihydro-8h-indeno[1,2-d]oxazolin-2-yl]pyridine

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货号

品牌

产品名称

规格

包装、参考价格

S854138

MACKLIN

2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-d]噁唑啉-2-基]吡啶

≥98%,99%e.e.

92元/250mg; 319元/1g; 1570元/5g;

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储存：室温,干燥

554626

J&K

2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine

95%

1425元/250MG; 4826元/1G;

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基本信息

分子式	C₂₅H₁₉N₃O₂
分子量	393.44
熔点	276-281
比旋光度([α]20D)	-410° to -340° (C=1, CH2Cl2)
MDL编码	MFCD05861599

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3

07-0280

Strem

(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

min. 97%

3156元/250mg; 10245元/1g;

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07-1367

Strem

(3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]

95%, (99% ee)

1680元/250mg;

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Y10426

Alfa Aesar

2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)

586元/100mg; 1177元/250mg;

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基本信息

分子量
393.44

673978

Sigma-Aldrich

2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

1121.37元/250 MG; 3952.74元/1 G;

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产品说明

应用

Reactant involved in synthesis of:

Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
Chiral N,N,N-tridentate pybos and pyboxazine ligands

包装

250 mg in glass insert
1 g in glass bottle

基本信息

经验(实验)分子式	C₂₅H₁₉N₃O₂
分子量	393.44
MDL编号	MFCD05861599
PubChem化学物质编号	329760573
NACRES	NA.22

产品性质

质量水平	100
旋光性	[α]20/D -375°, c = 1 in dichloromethane (typical)
mp	276-281 ℃
SMILES string	C1[C@H]2OC(=N[C@H]2c3ccccc13)c4cccc(n4)C5=N[C@@H]6[C@@H](Cc7ccccc67)O5
InChI	1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m1/s1
InChI key	BZSJUFJXCHHRHW-LUKWVAJMSA-N

安全信息

危险声明	H413
危险分类	Aquatic Chronic 4
储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

971507

Amethyst

2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine

98%, 用于合成

1405元/250MG; 4629元/1G;

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基本信息

分子式	C₂₅H₁₉N₃O₂
分子量	393.44
熔点	276-281
比旋光度([α]20D)	-375 (C=1, CH2Cl2)
MDL编码	MFCD05861599

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3

237544

Fluorochem

2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine

95%

2134元/250mg; 6402元/1g;

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基本信息

CAS Number	185346-09-2
MDL Number	MFCD05861599
Melting Point	265℃

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.