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CAS: 18531-95-8
分子式: C20H16N2
分子量: 284.36
熔点: 242-244℃
英文名称: 
(S)-(-)-2,2'-diamino-1,1'-binaphtyl
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S830357MACKLIN(S)-(-)-1,1'-联-2-萘胺99%35元/250mg;   67元/1g;   234元/5g;   1145元/25g;   展开
储存:室温,密封
状态:白色到灰白色固体
D3208TCI(S)-(-)-1,1'-Binaphthyl-2,2'-diamine>98.0%(T)(HPLC)1090元/200MG;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C20H16N2 = 284.36
外观与形状(20℃)固体
Reaxys-RN4354300
PubChem物质ID354334899
MDL编号MFCD00145204

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(HPLC)min. 98.0 area%
Optical purity(LC)min. 98.0 ee%
Purity(Nonaqueous Titration)min. 98.0 %
Melting point241.0 to 246.0 ℃

物性(参考值)

熔点244 ℃
比旋光度 [α]D-152° (C=1,Pyridine)
最大吸收波长368(H2O) nm

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
434863J&K(S)-(-)-1,1'-Binaphthyl-2,2'-diamine99%, ee: 99%356元/250MG;   1171元/1G;   4675元/5G;   展开

基本信息

分子式C20H16N2
分子量284.36
熔点242-244
比旋光度([α]20D) -158° to-154° (C=1, Pyridine)
MDL编码MFCD00145204
Beilstein2419071

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
07-0328Strem(S)-(-)-2,2'-Diamino-1,1'-binaphthyl99%862元/250mg;   2489元/1g;   展开
H25784Alfa Aesar(S)-(-)-1,1'-Bi(2-naphthylamine)97%1473元/250mg;   5714元/1g;   展开

基本信息

MDL
MFCD00145204

分子式
C20H16N2

分子量
284.36

熔点
236-242°

形态
Powder

Beilstein
2419071

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C35652Alfa Aesar(S)-(-)-2,2'-Diamino-1,1'-binaphthalene97%10575元/1g;   展开

基本信息

Ref#
35652

MDL
145204

分子式
C20 H16 N2

分子量
284.36

382434Sigma-Aldrich(S)-(-)-1,1′-Binaphthyl-2,2′-diamine99%1604.66元/1 G;   展开

产品说明

应用

用于合成手性内酯。
(S)-(-)-1,1′-Binaphthyl-2,2′-diamine may be used in the synthesis of (S)-(+)-N,N′-dimethyl-N,N′-bis{3-[bis-(1-methyl-2-benzimidazolyl methyl)]-amino]-propyl}-1,1′-binaphthyl-2,2′-diamine, an octadentate ligand that can form dinuclear and trinuclear copper(II) complexes. It may also be used in the synthesis of (Sa)-N-[2´-amino-(1,1´-binaphthyl)-2-yl]-4-methylbenzenesulfonamide.

包装

1 g in glass bottle

基本信息

线性分子式H2NC10H6C10H6NH2
分子量284.35
Beilstein2419071
MDL编号MFCD00145204
PubChem化学物质编号24863896
NACRESNA.22

产品性质

质量水平200
测定99%
旋光性[α]20/D −157°, c = 1 in pyridine
光学纯度ee: 99% (HPLC)
mp242-244 ℃ (lit.)
SMILES stringNc1ccc2ccccc2c1-c3c(N)ccc4ccccc34
InChI1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2
InChI keyDDAPSNKEOHDLKB-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
212800Fluorochem(S)-(-)-1,1'-Binaphthyl-2,2'-diamine95%1078元/1g;   3938元/5g;   展开

基本信息

CAS Number18531-95-8
MDL NumberMFCD00145204
Melting Point242 - 244 ℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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