CAS 1823217-44-2; tbaf(pin)<sub>2</sub>

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CAS:

1823217-44-2

英文名称:

tbaf(pin)₂

1-butanaminium, n,n,n-tributyl-, fluoride, compd. with 2,3-dimethyl-2,3-butanediol (1:2:2)

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货号

品牌

产品名称

规格

包装、参考价格

900021

Sigma-Aldrich

TBAF(pin)₂

422.9元/1 G;

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产品说明

一般描述

TBAF(pin)₂ is a fluoride–alcohol complex with coordination number four. It can be obtained by reacting pinacol (pin) with tetrabutylammonium fluoride trihydrate (TBAF(H₂O)₃). The geometric structure and bonding of TBAF(pin)₂ have been studied.

应用

Nucleophilic fluorinating reagent is a more convenient crystalline solid for handling and storage compared to tetrabutylammonium fluoride hydrate (Aldrich 241512). As reported by Engle and Gouverneur, these solids display comparable reactivity on similar substrates.

包装

1 g in glass bottle

其他说明

Coordination diversity in hydrogen-bonded homoleptic fluoride–alcohol complexes modulates reactivity

基本信息

经验(实验)分子式	C₂₈H₆₄FNO₄
分子量	497.81
PubChem化学物质编号	329769764

产品性质

形式	powder
质量水平	100
mp	162-167 ℃ (d)
SMILES string	OC(C)(C)C(C)(C)O.OC(C)(C)C(C)(C)O.CCCC[N+](CCCC)(CCCC)CCCC.[F-]
InChI	1S/C16H36N.2C6H14O2.FH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;21-5(2,7)6(3,4)8;/h5-16H2,1-4H3;27-8H,1-4H3;1H/q+1;;;/p-1
InChI key	CVEUWEZBMVLEKR-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

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