CAS 1822-51-1; 4-氯甲基吡啶盐酸盐; 4-(chloromethyl)pyridine hydrochloride

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货号

品牌

产品名称

规格

包装、参考价格

C804846

MACKLIN

4-(氯甲基)吡啶盐酸盐

97%

37元/5g; 100元/25g; 375元/100g; 1869元/500g;

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储存：2~8°C
状态：白色到棕色到橙色粉末或块状

C0805

TCI

4-(Chloromethyl)pyridine Hydrochloride

>98.0%(T)(HPLC)

140元/5G; 690元/25G; 5985元/250G;

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基本信息

纯度/分析方法	>98.0%(T)(HPLC)
分子式/分子量	C₆H₆ClN·HCl = 164.03
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (吸湿)
Reaxys-RN	3689154
PubChem物质ID	87565871
MDL编号	MFCD00012826

技术规格

Appearance	White to Orange to Green powder to crystal
Purity(HPLC)	min. 98.0 area%
Purity(Nonaqueous Titration)	min. 98.0 %

物性(参考值)

熔点

169 ℃

安全信息

图形或危害标志
信号词	危险
危险性说明	H314 : 造成严重皮肤灼伤和眼损伤。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P260 : 不要吸入粉尘或烟雾。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3261
类别	8
包装类别	III
监管条件代码(*)

280455

J&K

4-(Chloromethyl)pyridine Hydrochloride

98%

60元/5G; 144元/25G; 414元/100G;

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基本信息

分子式	C₆H₆ClN·HCl
分子量	164.03
熔点	166-173
MDL编码	MFCD00012826
Beilstein	3689154
EINECS 编号	217-350-7
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P280 P305+P351+P338 P314
UN号码	3261
危险分类	8
包装等级	III
WGK	3
TSCA	否

A12859

Alfa Aesar

4-(Chloromethyl)pyridine Hydrochloride

98%

384元/5g; 1477元/25g; 4999元/100g;

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应用
It finds its application as a reagent for protection of carboxyl termini of peptides as 4-picolyl esters, providing a polar 'handle' which aids in separation and purification of the peptide. The group can be introduced in the presence of a base, e.g. tetramethylguanidine, is stable to acid-catalyzed removal of Cbz protecting group and can be removed by base, Na in liquid ammonia or catalytic hydrogenolysis. It is also applied in conjunction with Amberlyst??15 resin in peptide synthesis. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

备注
Hygroscopic. Store away from oxidizing agents and bases. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00012826

EINECS
217-350-7

分子式
C₆H₆₂N?HCl

分子量
164.04

熔点
166-171°

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water (750 mg/ml at 20°C), soluble in 1N HCl (2.5%), DMSO, and methanol.

Beilstein
3689154

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H314-H318-H317
Toxic if swallowed.Toxic in contact with skin.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.

Precautionary Statements
P260h-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
21/22-34-43
Harmful in contact with skin and if swallowed.Causes burns.May cause sensitization by skin contact.

安全等级
24-26-36/37/39-45
Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
否

C13120

Alfa Aesar

4-Picolyl Chloride Hydrochloride

97%

765元/10g; 5466元/100g;

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基本信息

Ref#
13120

MDL
12826

分子式
C6 H6 Cl N . H Cl

分子量
164.04

安全信息

危险等级
8

包装组
III

P43807

Sigma-Aldrich

4-(Chloromethyl)pyridine Hydrochloride

97%

216.94元/10 G; 1405.98元/100 G;

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基本信息

经验(实验)分子式	C₆H₆ClN · HCl
分子量	164.03
Beilstein	3689154
EC 号	217-350-7
MDL编号	MFCD00012826
PubChem化学物质编号	24898533
NACRES	NA.22

产品性质

质量水平	100
测定	97%
mp	166-173 ℃ (lit.)
SMILES string	Cl[H].ClCc1ccncc1
InChI	1S/C6H6ClN.ClH/c7-5-6-1-3-8-4-2-6;/h1-4H,5H2;1H
InChI key	ZDHKVKPZQKYREU-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Skin Corr. 1B
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

465071

Amethyst

4-(Chloromethyl)pyridine Hydrochloride

98%, 用于合成

48元/5G; 100元/25G; 278元/100G; 1029元/500G;

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基本信息

分子式	C₆H₆ClN·HCl
分子量	164.03
熔点	166-173
MDL编码	MFCD00012826
Beilstein	3689154
EINECS 编号	217-350-7
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P280 P305+P351+P338 P314
UN号码	3261
危险分类	8
包装等级	III
WGK	3
TSCA	否

050512

Fluorochem

4-(Chloromethyl)pyridine hydrochlororide

97%

220元/1g; 220元/5g; 528元/25g; 1408元/100g;

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基本信息

CAS Number	1822-51-1
MDL Number	MFCD00012826
Melting Point	166-173℃

安全信息

图形或危害标志
危险性说明	H314: Causes severe skin burns and eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.