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CAS: 18115-70-3
分子式: C5H7LiO2
分子量: 106.05
沸点: 187.6ºC at 760 mmHg
熔点: 250ºC (dec.)(lit.)
英文名称: 
Lithiumacetylacetonate
用途: 用途:用作有机合成助剂,塑料添加剂。
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基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C5H7LiO2 = 106.05
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN4575087
PubChem物质ID87572044
SDBS (AIST Spectral DB)4124
MDL编号MFCD00013496

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点250 ℃(dec.)
最大吸收波长290(EtOH) nm
水溶性可溶

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
93-0361StremLithium Acetylacetonate98+%315元/10g;   945元/50g;   展开
030529Alfa AesarLithium 2,4-pentanedionate99.5%516元/10g;   1293元/50g;   5709元/250g;   展开

基本信息

MDL
MFCD00013496

EINECS
242-008-9

分子式
C5H7LiO2

分子量
106.05

熔点
ca 250°dec

形态
Crystalline

Beilstein
4575087

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332-H315-H319-H361-H335
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.Suspected of damaging fertility or the unborn child.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/37/38-63
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.Possible risk of harm to the unborn child.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

413046Sigma-AldrichLithium Acetylacetonate97%407.5元/25 G;   展开

产品说明

应用

乙酰丙酮锂[Li(acac)]被用于制备LiMn2O4 纳米粒子。 铝覆盖的Li(acac)被用作有机发光器件(OLED)中的有效电子注入层。 用于锂离子电池的电纺石墨烯嵌入的Li4Ti5O12纳米纤维的制备已有报道。

包装

25 g in glass bottle

基本信息

线性分子式CH3COCH=C(OLi)CH3
分子量106.05
Beilstein4575087
EC 号242-008-9
MDL编号MFCD00013496
PubChem化学物质编号24865838
NACRESNA.23

产品性质

质量水平200
测定97%
形式solid
reaction suitabilitycore: lithium
mp250 ℃ (dec.) (lit.)
SMILES string[Li+].C\C([O-])=C\C(C)=O
InChI1S/C5H8O2.Li/c1-4(6)3-5(2)7;/h3,6H,1-2H3;/q;+1/p-1/b4-3-;
InChI keyJTEOOCAGEXVCBQ-LNKPDPKZSA-M

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 + H312 + H332 - H315 - H319 - H335 - H361
预防措施声明P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
544309FluorochemLithium Acetylacetonate98%220元/5g;   396元/25g;   展开

基本信息

CAS Number18115-70-3
MDL NumberMFCD00013496
Melting Point250 ℃ (dec.)

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H361: Suspected of damaging fertility or the unborn child ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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