CAS 1803239-46-4; (R)-n-((S)-1-(二苯基膦基)-3-甲基丁-2-基)-2-甲基丙烷-2-亚磺酰胺; (R)-n-((S)-1-(diphenylphosphanyl)-3-methylbutan-2-yl)-2-methylpropane-2-sulfinamide

CAS:

1803239-46-4

分子式:

C₂₁H₃₀NOPS

分子量:

375.51

中文名称:

(R)-n-((S)-1-(二苯基膦基)-3-甲基丁-2-基)-2-甲基丙烷-2-亚磺酰胺

英文名称:

(R)-n-((S)-1-(diphenylphosphanyl)-3-methylbutan-2-yl)-2-methylpropane-2-sulfinamide

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货号

品牌

产品名称

规格

包装、参考价格

S938771

MACKLIN

[S（R）]-N-[（1S）-1-[（二苯基膦基）甲基]-2-甲基丙基]-2-甲基-2-丙亚磺酰胺

95%

104元/5mg; 467元/25mg; 1319元/100mg;

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储存：室温，惰性气体

9025921

J&K

(R)-N-((S)-1-(Diphenylphosphanyl)-3-methylbutan-2-yl)-2-methylpropane-2-sulfinamide

97%

2400元/100MG;

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基本信息

15-8376

Strem

[S(R)]-N-[(1S)-1-[(Diphenylphosphino)methyl]-2-methylpropyl]-2-methyl-2-Propanesulfinamide

95%

2145元/50mg;

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Technical Notes:

1.Sulfinamide phos phine organocatalyst for the enantioselective intramolecular Rauhut-Currier reaction.

2.Used in phosphine-catalyzed asymmetric intermolecular cross-vinylogous Rauhut-Currier Reactions of vinyl Ketones with para-quinone methides.

3.Used in the enantios elective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates.

References:

1.Angew. Chem. Int. Ed. 2015, 54, 6874.

2.ACS Catal. 2017, 7, 2805.

3.Org. Lett. 2017, 19, 6080.

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