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CAS: 1803239-44-2
分子式: C24H28NOPS
分子量: 409.5
中文名称: 
(R)-n-((S)-2-(二苯基膦基)-1-苯乙基)-2-甲基丙烷-2-亚磺酰胺
英文名称: 
(R)-n-((S)-2-(diphenylphosphanyl)-1-phenylethyl)-2-methylpropane-2-sulfinamide
推荐供应商
货号品牌产品名称规格包装、参考价格
S938770MACKLIN[S(R)]-N-[(1S)-2-(二苯基膦基)-1-苯基乙基]-2-甲基-2-丙烷亚磺酰胺95%41元/5mg;   166元/25mg;   469元/100mg;   咨询
储存:室温,惰性气体
9025909J&K(R)-N-((S)-2-(Diphenylphosphanyl)-1-phenylethyl)-2-methylpropane-2-sulfinamide97%1600元/100MG;   咨询

基本信息

分子式C24H28NOPS
分子量409.52
15-8366Strem[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-phenylethyl]-2-methyl-2-propanesulfinamide95%2220元/100mg;   咨询

Technical Notes:

1.Sulfinamide phos phine organocatalyst for the enantioselective intramolecular Rauhut-Currier reaction.

2.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1,3-dienes with vinyl ketones.

3.Used in the enantioselective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates.

4.L igand for the direct Pd-catalyzed cross-coupling reaction of easily accessible secondary phosphine oxides and aryl bromides, which provides rapid access to P-chiral phosphine oxides.

References:

1. Angew. Chem. Int. Ed. 2015, 54, 6874.

2.Org. Lett. 2017, 19, 1710.

3.Org. Lett. 2017, 19, 6080.

4.J. Am. Chem. Soc. 2019, 141, 20556.

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