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CAS: 1765-93-1
分子式: C6H6BFO2
分子量: 139.92
熔点: 263-265℃
中文名称: 
4-氟苯硼酸
对氟苯硼酸
英文名称: 
p-Fluorophenylboronic acid
4-Fluorobenzeneboronic acid
4-fluorophenylboronic acid
推荐供应商
货号品牌产品名称规格包装、参考价格
F809682MACKLIN4-氟苯硼酸98%29元/1g;   31元/5g;   61元/25g;   220元/100g;   1068元/500g;   咨询
储存:2~8°C
状态:白色到浅黄色粉末
F0361TCI4-Fluorophenylboronic Acid (contains varying amounts of Anhydride)150元/5G;   500元/25G;   咨询

基本信息

分子式/分子量C6H6BFO2 = 139.92
外观与形状(20℃)固体
Reaxys-RN2829653
PubChem物质ID87570132
MDL编号MFCD00039136

技术规格

AppearanceWhite to Light yellow to Light red powder to crystal
Purity(Neutralization titration)97.0 to 116.0 %

物性(参考值)

熔点265 ℃
水溶性微溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
168063J&K4-Fluorophenylboronic acid98%60元/1G;   77元/5G;   214元/25G;   咨询

基本信息

分子式C6H6BFO2
分子量139.92
熔点262-265
MDL编码MFCD00039136
Beilstein2829653

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
05-0800Strem4-Fluorophenylboronic acidmin. 97%931元/5g;   3671元/25g;   咨询
A15991Alfa Aesar4-Fluorobenzeneboronic acid97%434元/1g;   1652元/5g;   3062元/25g;   咨询

基本信息

MDL
MFCD00039136

分子式
C6H6BFO2

分子量
139.92

熔点
260-265°

灵敏度
Ambient temperatures.

形态
Crystalline powder

Beilstein
2829653

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C33410Alfa Aesar4-Fluorophenylboronic acid97%574元/1g;   1061元/5g;   3550元/25g;   咨询

基本信息

Ref#
33410

MDL
39136

分子式
C6 H6 B F O2

分子量
139.92

417556Sigma-Aldrich4-Fluorophenylboronic acid≥95%130.36元/1 G;   201.08元/5 G;   886.1元/25 G;   咨询

产品说明

应用

4-氟基苯硼酸可用作反应物,参与四氟硼酸芳香重氮盐、 碘鎓盐和碘烷的偶联反应。它还被用于生产具有生物活性的新型三联苯。
它也可作为反应物参与:

  • 使用微波和triton B催化剂的Suzuki偶联。
  • Pd催化的吡唑与苯硼酸的直接芳基化反应。
  • 钯纳米粒子催化的 Mizoroki-Heck 和 Suzuki-Miyaura 偶联反应。
  • Cu催化的Petasis反应。
  • 串联型Pd(II)催化的氧化Heck反应和分子内C-H酰胺化序列。
  • 钌催化的直接芳基化。
  • Rh催化的不对称耦合物加合。
  • 无配体铜催化的硝基芳烃与芳基硼酸的偶联。
  • 通过Suzuki-Miyaura和Sonogashira交叉偶联反应进行区域选择性芳基化和炔基化。
  • 四溴噻吩的Suzuki交叉偶联。
  • 腈的钯催化加成。

包装

1, 5 g in glass bottle
25 g in poly bottle

其他说明

含不定量的酸酐

基本信息

线性分子式FC6H4B(OH)2
分子量139.92
Beilstein2829653
MDL编号MFCD00039136
PubChem化学物质编号24866160
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式powder
mp262-265 ℃ (lit.)
SMILES stringOB(O)c1ccc(F)cc1
InChI1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChI keyLBUNNMJLXWQQBY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
303580Amethyst4-Fluorophenylboronic acid98%, 用于合成71元/5G;   114元/25G;   313元/100G;   咨询

基本信息

分子式C6H6BFO2
分子量139.92
熔点262-265
MDL编码MFCD00039136
Beilstein2829653

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
006182Fluorochem4-Fluorobenzeneboronic acid97%220元/5g;   528元/25g;   1188元/100g;   咨询

基本信息

CAS Number1765-93-1
MDL NumberMFCD00039136
Melting Point267-270℃
Density1.24

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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