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CAS: 1765-40-8
分子式: C7H2BrF5
分子量: 260.99
沸点: 174-175℃
熔点: 19-175℃
中文名称: 
ALPHA-溴-2,3,4,5,6-五氟甲苯
2,3,4,5,6-五氟苯甲基溴
2,3,4,5,6-五氟溴化苄
英文名称: 
2,3,4,5,6-Pentafluorobenzyl bromide
α-Bromo-2,3,4,5,6-pentafluorotoluene
à-Bromo-2,3,4,5,6-pentafluorotoluene
pentafluorobenzyl bromide
alpha-bromo-2,3,4,5,6-pentafluorotoluene
推荐供应商
货号品牌产品名称规格包装、参考价格
P815849MACKLIN2,3,4,5,6-五氟溴苄98%65元/1g;   181元/5g;   858元/25g;   2930元/100g;   11740元/500g;   咨询
储存:室温,密封
状态:无色到黄色到棕色液体或固体
折射率:n20/D 1.471(lit.)
P890222MACKLIN2,3,4,5,6-五氟溴苄用于GC衍生化,99%299元/1g;   979元/5g;   3140元/25g;   10020元/100g;   咨询
储存:室温,密封
状态:无色到黄色到棕色液体或固体
折射率:n20/D 1.471(lit.)
P0809TCIPentafluorobenzyl Bromide>98.0%(GC)235元/1G;   640元/5G;   1420元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7H2BrF5 = 260.99
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN647808
PubChem物质ID87574940
SDBS (AIST Spectral DB)5105
MDL编号MFCD00000299

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

熔点18 ℃
沸点176 ℃
闪点83 ℃
比重1.85
折射率1.47

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 II
监管条件代码(*)
278435J&Kα-Bromo-2,3,4,5,6-pentafluorotoluene98%263元/5G;   967元/25G;   咨询

基本信息

分子式C7H2BrF5
分子量260.99
熔点19-20
沸点174-175
闪点82
密度1.728
折光率(n20D)1.4700-1.4720
MDL编码MFCD00000299
Beilstein647808
EINECS 编号217-182-4
存储条件Corrosives

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
H318
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK3
09-5550StremPentafluorobenzylbromide98+%265元/1g;   876元/5g;   3531元/25g;   咨询
A11623Alfa Aesar2,3,4,5,6-Pentafluorobenzyl bromide97%488元/5g;   1918元/25g;   6192元/100g;   咨询

应用
2,3,4,5,6-Pentafluorobenzyl bromide is used as a reagent for derivatization of alcohols, carboxylic acids, sulfonamides for GC and polyfunctional thiols. It is used for the preparation of pentafluorobenzyl esters of organic acids for determination by capillary and GC. It is also used to derivatize N-7-substituted guanine adducts of DNA for determination by GC-electron capture-MS.

备注
Store in a cool, dry, well-ventilated area. Incompatible with bases and oxidizing agents. Store at 4?°C. Protected from moisture.

基本信息

MDL
MFCD00000299

EINECS
217-182-4

分子式
C7H2BrF5

分子量
261.00

熔点
18-20°

沸点
174-175°

闪点
83°(181°F)

密度
1.844

折射率
1.4720

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Hydrolyzes in water.

Beilstein
647808

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C14633Alfa Aesaralpha-Bromo-2,3,4,5,6-pentafluorotoluene97%802元/5g;   1345元/10g;   4587元/50g;   咨询

基本信息

Ref#
14633

MDL
299

分子式
C7 H2 Br F5

分子量
260.98

闪点
82

密度
1.72

安全信息

危险等级
8

包装组
II

101052Sigma-Aldrich2,3,4,5,6-Pentafluorobenzyl bromide99%326.65元/1 G;   512.03元/5 G;   1629.43元/25 G;   咨询

产品说明

包装

1, 5, 25 g in glass bottle

应用

制备有机酸的五氟苄酯,以用于毛细管和气相色谱测定。也可用于 DNA 的 N-7-取代鸟嘌呤加合物的衍生化,以用于 GC-ECD-MS 测定。
多官能硫醇气相色谱分析的衍生化试剂。

基本信息

线性分子式C6F5CH2Br
分子量260.99
Beilstein647808
EC 号217-182-4
MDL编号MFCD00000299
PubChem化学物质编号24846531
NACRESNA.22

产品性质

质量水平200
测定99%
折射率n20/D 1.471 (lit.)
bp174-175 ℃ (lit.)
mp19-20 ℃ (lit.)
密度1.728 g/mL at 25 ℃ (lit.)
SMILES stringFc1c(F)c(F)c(CBr)c(F)c1F
InChI1S/C7H2BrF5/c8-1-2-3(9)5(11)7(13)6(12)4(2)10/h1H2
InChI keyXDEPVFFKOVDUNO-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)181.4 °F
闪点(C)83 ℃
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
90257Supelco2,3,4,5,6-Pentafluorobenzyl bromidefor GC derivatization, LiChropur, ≥98.5% (GC)646.31元/1 G;   1627.41元/5 G;   咨询

产品说明

应用

Learn more in the Product Information
It is used for the analysis of D2/E2-isoprostanes using negative ion chemical ionization-gas chromatography/mass spectrometry (NICI-GC/MS). Fatty acids may be converted to pentafluorobenzyl esters using PFG-Br and diisopropylethylamine during determination of fatty acids using NICI-GC/MS.

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

基本信息

线性分子式C6F5CH2Br
分子量260.99
Beilstein647808
MDL编号MFCD00000299
NACRESNA.05

产品性质

质量水平100
等级for GC derivatization
测定≥98.5% (GC)
质量LiChropur
reaction suitabilityreagent type: derivatization reagent
reaction type: Acylations
technique(s)gas chromatography (GC): suitable
折射率n20/D 1.471 (lit.)
bp174-175 ℃ (lit.)
mp19-20 ℃ (lit.)
密度1.728 g/mL at 25 ℃ (lit.)
SMILES stringFc1c(F)c(F)c(CBr)c(F)c1F
InChI1S/C7H2BrF5/c8-1-2-3(9)5(11)7(13)6(12)4(2)10/h1H2
InChI keyXDEPVFFKOVDUNO-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)181.4 °F
闪点(C)83 ℃
8.41643Sigma-Aldrich2,3,4,5,6-Pentafluorobenzylbromidefor synthesis1289.3元/5 ML;   咨询

产品说明

分析说明

Assay (GC, area%): ≥ 97.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.845 - 1.855
Identity (IR): passes test
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

基本信息

经验(实验)分子式C7H2BrF5
分子量260.99
MDL编号MFCD00000299
EC索引号217-182-4

产品性质

质量水平200
测定≥97.0% (GC)
转变温度flash point 83 ℃
密度1.85 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C7H2BrF5/c8-1-2-3(9)5(11)7(13)6(12)4(2)10/h1H2
InChI keyXDEPVFFKOVDUNO-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)181.4 °F
闪点(C)83 ℃
001353Fluorochem2,3,4,5,6-Pentafluorobenzyl bromide99%484元/10g;   990元/25g;   2464元/100g;   咨询

基本信息

CAS Number1765-40-8
MDL NumberMFCD00000299
Boiling Point174-175℃
Melting Point18-20℃
Density1.728

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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