[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 17564-64-6
关键词:       仅模糊查询
CAS: 17564-64-6
分子式: C9H6ClNO2
分子量: 195.60
熔点: 131-135 °C(lit.)
中文名称: 
N-氯甲基苯甲酰亚胺
N-氯甲基邻苯二甲酰亚胺
英文名称: 
1H-Isoindole-1,3(2H)-dione,2-(chloromethyl)-
N-(Chloromethyl)phthalimide
2-(chloromethyl)-1h-isoindole-3(2h)-dione
性质描述: 淡黄色结晶。熔点134-135℃(136.5℃)不溶于水,溶于热醇、冰醋酸、乙酸乙酯。
生产方法: 由苯酐与碳酸氢铵反应得到邻苯二甲酰亚胺后,再经羟化、氯化而得。1.邻二甲酰亚胺的制备将苯酐和碳酸氢铵反应,得邻苯二甲酰亚胺。2.N-羟甲基苯二甲酰亚胺的制备将甲醛与邻苯二甲酰亚胺反应得N-羟甲基苯二甲酰亚胺。3.氯代甲基苯甲酰亚胺的制备将N-羟甲基苯二甲酰亚胺制得N-氯甲基苯甲酰亚胺。
用途: 农药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N815098MACKLINN-(氯甲基)邻苯二甲酰亚胺95%32元/5g;   100元/25g;   396元/100g;   展开
储存:室温
A5504TCIN-Chloromethylphthalimide [for HPLC Labeling]>98.0%(T)(HPLC)1180元/5G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C9H6ClNO2 = 195.60
外观与形状(20℃)固体
Reaxys-RN140942
PubChem物质ID87563154
SDBS (AIST Spectral DB)23200
MDL编号MFCD00005898

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Argentometric Titration)min. 98.0 %
Melting point133.0 to 137.0 ℃
Solubility in hot Methanolalmost transparency
Effect test of HPLC derivatizationEffective as labeling agent for Hexanoic Acid , Decanoic Acid , Dodecanoic Acid

物性(参考值)

熔点135 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
254972J&KN-(Chloromethyl)phthalimide97%235元/5G;   867元/25G;   3240元/100G;   展开

基本信息

分子式C9H6ClNO2
分子量195.60
熔点131-135
MDL编码MFCD00005898
Beilstein140942
EINECS 编号241-541-4

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H317
H319
H335
防范说明P261
P280
P301+P310
P305+P351+P338
UN号码2811
危险分类6.1
包装等级III
WGK3
TSCA
A12018Alfa AesarN-(Chloromethyl)phthalimide97%1603元/25g;   3628元/100g;   展开

应用
It is used as an agrochemical and medicine intermediates and is used in organic synthesis. Microporous membranes prepared from chemically modified polysulfone, which is a derivative of this compound have better streaming potential.

备注
Store in cool place. Keep away from oxidizing agents. Incompatible with bases.

基本信息

MDL
MFCD00005898

EINECS
241-541-4

分子式
C9H6ClNO2

分子量
195.61

熔点
131-135°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Insoluble in water.

Beilstein
140942

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

232424Sigma-AldrichN-(Chloromethyl)phthalimide97%632.21元/10 G;   1613.58元/50 G;   展开

产品说明

应用

N-(Chloromethyl)phthalimide was used:

  • in the synthesis of aminomethyl copoly-(styrene-l%-divinylbenzene) resins of high purity
  • in esterification of 12S-hydroxylabda-8(17),13(16),14-trien-19-oic acid, new labdane-type diterpenoid
  • in esterification of 13-ethoxylabda-8(17),11,14-trien-19-oicacid, new labdane-type diterpenoid

包装

10, 50 g in poly bottle

基本信息

经验(实验)分子式C9H6ClNO2
分子量195.60
Beilstein140942
EC 号241-541-4
MDL编号MFCD00005898
PubChem化学物质编号24853898
NACRESNA.22

产品性质

质量水平200
测定97%
形式powder
mp131-135 ℃ (lit.)
溶解性chloroform: soluble 50 mg/mL
SMILES stringClCN1C(=O)c2ccccc2C1=O
InChI1S/C9H6ClNO2/c10-5-11-8(12)6-3-1-2-4-7(6)9(11)13/h1-4H,5H2
InChI keyJKGLRGGCGUQNEX-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H315 - H317 - H319 - H335
预防措施声明P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
049885FluorochemN-(Chloromethyl)phthalimide97%242元/1g;   660元/10g;   1298元/25g;   4466元/100g;   展开

基本信息

CAS Number17564-64-6
MDL NumberMFCD00005898
Melting Point131 - 135 ℃

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9