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CAS: 174899-66-2
分子式: C9H15F3N2O3S
分子量: 288.28
熔点: 16°C
中文名称: 
1-正-丁基-3-甲基咪唑鎓 三氟甲烷磺酸盐
英文名称: 
1-butyl-3-methylimidazolium trifluoromethansulfonate
1-n-Butyl-3-methylimidazolium triflate
1-n-Butyl-3-methylimidazolium trifluoromethanesulfonate
1-Butyl-3-methylimidazolium trifluoromethanesulfonate
推荐供应商
货号品牌产品名称规格包装、参考价格
B802816MACKLIN1-丁基-3-甲基咪唑三氟甲磺酸盐97%28元/1g;   49元/5g;   169元/25g;   644元/100g;   咨询
储存:2-8℃
状态:无色到黄色到棕色到绿色澄清液体
折射率:1.434
B2337TCI1-Butyl-3-methylimidazolium Trifluoromethanesulfonate>98.0%(N)395元/5G;   1790元/25G;   咨询

基本信息

纯度/分析方法>98.0%(N)
分子式/分子量C9H15F3N2O3S = 288.29
外观与形状(20℃)液体
Reaxys-RN8806425
PubChem物质ID87565162
MDL编号MFCD03427620

技术规格

AppearanceColorless to Yellow to Green clear liquid
Purity(HPLC)min. 95.0 area%
Purity(with Total Nitrogen)min. 98.0 %

物性(参考值)

熔点16 ℃
比重1.31
折射率1.44

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
523922J&K1-Butyl-3-methylimidazolium Trifluoromethanesulfonate99%430元/5G;   536元/25G;   1395元/100G;   咨询

基本信息

分子式C9H15F3N2O3S
分子量288.29
熔点16.4
闪点>100
密度1.292
折光率(n20D)1.4370-1.4420
MDL编码MFCD03427620
Beilstein8806425

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H319
防范说明P301+P310
P305+P351+P338
UN号码2810
危险分类6.1
包装等级III
WGK3
TSCA
L19765Alfa Aesar1-n-Butyl-3-methylimidazolium trifluoromethanesulfonate98%916元/2g;   3212元/10g;   咨询

基本信息

MDL
MFCD03427620

EINECS
000-000-0

分子式
C9H15F3N2O3S

分子量
288.29

熔点
16°

闪点
None

密度
1.295

折射率
1.4390

灵敏度
Hygroscopic. Ambient temperatures.

形态
Viscous liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319
Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.

安全信息

危险类别
36/38
Irritating to eyes and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

711772Sigma-Aldrich1-Butyl-3-methylimidazolium Trifluoromethanesulfonate97%2109.79元/100 G;   咨询

产品说明

一般描述

1-Butyl-3-methylimidazolium trifluoromethanesulfonate [bmim][OTf] is a versatile ionic liquid commonly used in synthetic chemistry.

应用

[bmim][OTf] can be used as:       

  • A glycosylation promoter in the synthesis of oligosaccharides from thiophenyl and trichloroacetimidate glycoside donors.      
  •  A solvent for the extraction of sulfur and nitrogen containing aromatic organic compounds from aliphatic hydrocarbons.
  •   A reagent in the preparation of ion-conductive polymeric membranes.        
  • A dopant in the synthesis of poly (ethyl methacrylate) based polymer electrolytes to increase the ionic conductivity.
  •  A reaction medium to synthesize aryl ketones by Friedel–Crafts benzoylation of aryl compounds by using bismuth triflate as a catalyst.

包装

100 g in glass bottle
1 kg in glass bottle

基本信息

经验(实验)分子式C9H15F3N2O3S
分子量288.29
MDL编号MFCD03427620
PubChem化学物质编号329763088
NACRESNA.22

产品性质

质量水平100
测定97%
形式liquid
杂质≤0.5% water
折射率n20/D 1.434
密度1.292 g/mL at 20 ℃ (lit.)
SMILES string[O-]S(=O)(=O)C(F)(F)F.CCCCn1cc[n+](C)c1
InChI1S/C8H15N2.CHF3O3S/c1-3-4-5-10-7-6-9(2)8-10;2-1(3,4)8(5,6)7/h6-8H,3-5H2,1-2H3;(H,5,6,7)/q+1;/p-1
InChI keyFRZPYEHDSAQGAS-UHFFFAOYSA-M

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 - H315 - H319 - H411
预防措施声明P264 - P270 - P273 - P301 + P310 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)212.0 °F
闪点(C)> 100 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
76420Sigma-Aldrich1-Butyl-3-methylimidazolium Trifluoromethanesulfonate≥95.0% (H-NMR)296.85元/5 G;   837.19元/25 G;   咨询

产品说明

一般描述

1-丁基-3-甲基咪唑三氟甲磺酸酯是一种非质子 中性离子液体。

应用

在Diels-Alder反应中,1-丁基-3-甲基咪唑三氟甲磺酸酯可以用作高氯酸锂-乙醚混合物的替代品。

包装

5, 25 g in poly bottle

基本信息

经验(实验)分子式C9H15F3N2O3S
分子量288.29
MDL编号MFCD03427620
PubChem化学物质编号57652635
NACRESNA.22

产品性质

质量水平100
测定≥95.0% (H-NMR)
形式liquid
折射率n20/D 1.434
密度1.292 g/mL at 20 ℃ (lit.)
SMILES string[O-]S(=O)(=O)C(F)(F)F.CCCCn1cc[n+](C)c1
InChI1S/C8H15N2.CHF3O3S/c1-3-4-5-10-7-6-9(2)8-10;2-1(3,4)8(5,6)7/h6-8H,3-5H2,1-2H3;(H,5,6,7)/q+1;/p-1
InChI keyFRZPYEHDSAQGAS-UHFFFAOYSA-M

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 - H315 - H319 - H411
预防措施声明P264 - P270 - P273 - P301 + P310 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)212.0 °F
闪点(C)> 100 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
050261Fluorochem1-Butyl-3-methylimidazolium trifluoromethane sulfonate>98.0%(N)1848元/5g;   6600元/25g;   咨询

基本信息

CAS Number174899-66-2
MDL NumberMFCD03427620
Melting Point16℃
Density1.31

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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