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CAS: 174501-64-5
分子式: C8H15F6N2P
分子量: 284.18
沸点: >340°C
熔点: 6.5℃
中文名称: 
1-丁基-3-甲基六氟磷酸盐咪唑啉嗡
1-正-丁基-3-甲基咪唑鎓六氟磷酸盐
1-丁基-3-甲基咪唑六氟磷酸盐
1-丁基-3-甲基六氟磷酸盐咪唑嗡
英文名称: 
BMIMPF6
1-n-Butyl-3-methylimidazolium hexafluorophosphate
1-butyl,3-methylimidazolium hexfluorophosphate
1-butyl-3-methylimidazolium hexafluorophosphate
推荐供应商
货号品牌产品名称规格包装、参考价格
B802491MACKLIN1-丁基-3-甲基咪唑六氟磷酸盐97%30元/5g;   60元/25g;   210元/100g;   782元/500g;   3500元/2.5kg;   咨询
储存:2-8℃
状态:无色到黄色液体
折射率:n20/D 1.41
B2320TCI1-Butyl-3-methylimidazolium Hexafluorophosphate>98.0%(HPLC)(N)295元/5G;   830元/25G;   咨询

基本信息

纯度/分析方法>98.0%(HPLC)(N)
分子式/分子量C8H15F6N2P = 284.19
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN8026031
PubChem物质ID87565152
Merck Index (14)1581
MDL编号MFCD03093295

技术规格

Purity(HPLC)min. 98.0 area%
Purity(with Total Nitrogen)min. 98.0 %

物性(参考值)

比重1.37
折射率1.41
水溶性完全混溶
溶解性(不溶于)甲苯

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
124582J&K1-Butyl-3-methylimidazolium Hexafluorophosphate99%269元/5G;   593元/25G;   1780元/100G;   咨询

基本信息

分子式C8H15F6N2P
分子量284.18
沸点˃340
密度1.38
折光率(n20D)1.4090-1.4130
MDL编码MFCD03093295
Beilstein8026031
Merck14,1581

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA否
L19086Alfa Aesar1-n-Butyl-3-methylimidazolium hexafluorophosphate98+%1394元/5g;   2928元/25g;   4144元/100g;   咨询

应用
1-n-Butyl-3-methylimidazolium hexafluorophosphate is used as a solvent in headspace gas chromatography and countercurrent chromatography, as mobile and stationary phases. It is widely used in organic synthesis, extraction technologies, electochemistry and biphasic organometallic catalysis.

备注
Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD03093295

EINECS
000-000-0

分子式
C8H15F6N2P

分子量
284.19

熔点
8-10°

沸点
>350°

密度
1.365

折射率
1.4115

灵敏度
Hygroscopic. Ambient temperatures.

溶解性
Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.

Merck
14,1581

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C35417Alfa Aesar1-Butyl-3-methylimidazolium Hexafluorophosphate98+%1702元/5g;   2712元/25g;   7069元/100g;   咨询

基本信息

Ref#
35417

MDL
03093295

分子式
C8 H15 N2 . P F6

分子量
284.18

密度
13727

18122Sigma-Aldrich1-Butyl-3-methylimidazolium Hexafluorophosphatefor catalysis, ≥98.5% (T)1174.91元/5 G;   9396.62元/50 G;   咨询

产品说明

一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处以获取更多信息。
1-丁基-3-甲基咪唑鎓六氟磷酸盐是一种高纯度离子液体(HPIL),水和卤素含量低,是过渡金属催化反应的一种有效溶剂。它的一些其他优势包括疏水性和缺乏蒸气压。

应用

用于催化的离子液体

包装

5, 50 g in glass bottle

基本信息

经验(实验)分子式C8H15F6N2P
分子量284.18
MDL编号MFCD03093295
PubChem化学物质编号329751629
NACRESNA.22

产品性质

质量水平100
等级for catalysis
测定≥98.5% (T)
环保替代产品特性Safer Solvents and Auxiliaries
Catalysis
Learn more about the Principles of Green Chemistry.
杂质≤0.02% water
折射率n20/D 1.41
密度1.38 g/mL at 20 ℃ (lit.)
痕量阴离子bromide (Br-): ≤10 mg/kg
chloride (Cl-): ≤10 mg/kg
nitrate (NO3-): ≤10 mg/kg
phosphate (PO43-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg
环保替代产品分类Aligned
SMILES stringF[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1
InChI1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
InChI keyIXQYBUDWDLYNMA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
70956Sigma-Aldrich1-Butyl-3-methylimidazolium Hexafluorophosphate≥97.0% (HPLC)690.7元/5 G;   2484.05元/50 G;   7262.51元/250 G;   咨询

产品说明

一般描述

1-丁基-3-甲基咪唑六氟磷酸盐是一种基于咪唑的疏水性室温离子液体 (RTIL)。 可由 1-甲基咪唑与氯丁烷反应制得。气态氢氟碳化合物 (HFCs) 如氟甲烷、氟乙烷和 1,1,2,2-四氟乙烷可溶于 BMIMPF 6 。

应用

1-丁基-3-甲基咪唑六氟磷酸盐是一种在许多环境友好反应中使用的离子液体。

它也可以作为反应的介质,例如:

  • 二烯和烯炔底物在新型可回收钌卡宾配合物存在下的关环复分解反应。
  • 乙酰丙酮镍 (II) 催化芳香醛氧化为相应的的酸,氧化剂为双氧水。
  • 脂肪酶催化烯丙醇的对映选择性酰化反应。
  • 用四烯丙基锡烷对醛进行烯丙基化,生成高烯丙基醇。

包装

5, 50, 250 g in glass bottle

基本信息

经验(实验)分子式C8H15F6N2P
分子量284.18
MDL编号MFCD03093295
PubChem化学物质编号57652268
NACRESNA.22

产品性质

质量水平200
测定≥97.0% (HPLC)
折射率n20/D 1.411 (lit.)
密度1.38 g/mL at 20 ℃ (lit.)
SMILES stringF[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1
InChI1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
InChI keyIXQYBUDWDLYNMA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
958398Amethyst1-Butyl-3-methylimidazolium Hexafluorophosphate99%, 用于合成58元/5G;   195元/25G;   506元/100G;   咨询

基本信息

分子式C8H15F6N2P
分子量284.18
沸点˃340
密度1.38
折光率(n20D)1.4090-1.4130
MDL编码MFCD03093295
Beilstein8026031
Merck14,1581

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA否
217618Fluorochem1-Butyl-3-methyl-1H-imidazol-3-ium hexafluorophosphate(V)95%220元/10g;   440元/25g;   1232元/100g;   咨询

基本信息

CAS Number174501-64-5
MDL NumberMFCD03093295
Density1.38

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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