| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| B803097 | MACKLIN | 1,3 -双( 2,4,6 -三甲苯基)氯化咪唑鎓 | 97% | 26元/200mg; 36元/1g; 120元/5g; 580元/25g; 2230元/100g; | 展开 |
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| B3158 | TCI | 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride | >98.0%(T)(HPLC) | 695元/1G; 1990元/5G; | 展开 |
基本信息 | 纯度/分析方法 | >98.0%(T)(HPLC) | | 分子式/分子量 | C21H27ClN2 = 342.91 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (吸湿) | | Reaxys-RN | 7455488 | | PubChem物质ID | 87560276 | | MDL编号 | MFCD09039279 |
技术规格 | Appearance | White to Light yellow powder to crystal | | Purity(HPLC) | min. 98.0 area% | | Purity(Nonaqueous Titration) | min. 98.0 % |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染:用水充分清洗。 P337 + P313 : 如仍觉眼刺激:求医/就诊。 P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激:求医/就诊。
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| 07-4011 | Strem | 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride | min. 97% | 705元/500mg; 2100元/2g; | 展开 |
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| C37833 | Alfa Aesar | 1,3-Bis(2,4,6-trimethylphenyl)imidazolidinium chloride | 97% | 1674元/1g; 7731元/5g; | 展开 |
基本信息 Ref# 37833 MDL 09039279 分子式 C21 H27 Cl N2 分子量 342.91 |
| 656631 | Sigma-Aldrich | 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride | 95% | 359.22元/1 G; 1020.86元/5 G; | 展开 |
产品说明 一般描述 1,3-双(2,4,6-三甲基苯基)咪唑啉氯化物是一种 NHC(N-杂环卡宾)配体,其可与金属预催化剂结合形成具有高催化活性的络合物。 应用 N-杂环卡宾配体
N-杂环卡宾催化剂前体用于:
- 叠氮化物与末端乙炔的区域选择性环加成反应,生成 1,4-二取代的三唑。内部乙炔也可与该催化剂一起使用。
- Markovnikov 型末端炔烃的水合作用
- 酮的氢化硅烷化和叠氮化物和炔烃的环加成
- Suzuki-Miyaura 反应
- 发光实验
包装 1, 5 g in glass bottle 基本信息 | 经验(实验)分子式 | C21H27ClN2 | | 分子量 | 342.91 | | MDL编号 | MFCD09039279 | | PubChem化学物质编号 | 24884213 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 95% | | reaction suitability | reagent type: ligand | | mp | 280-286 ℃ | | SMILES string | [Cl-].Cc1cc(C)c(N2CC[N+](=C2)c3c(C)cc(C)cc3C)c(C)c1 | | InChI | 1S/C21H27N2.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;/h9-13H,7-8H2,1-6H3;1H/q+1;/p-1 | | InChI key | COGMCBFILULEOS-UHFFFAOYSA-M |
安全信息 | 象形图 |  | | 警示用语: | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 10 - Combustible liquids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
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| 036862 | Fluorochem | 1,3-Bis-(2,4,6-trimethylphenyl)imidazolidiniumchloride | 97% | 1342元/1g; 4664元/5g; | 展开 |
基本信息 | CAS Number | 173035-10-4 | | MDL Number | MFCD09039279 | | Melting Point | 286℃ |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .
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