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CAS: 173035-10-4
分子式: C21H27ClN2
分子量: 342.91
熔点: 280-286 ℃
英文名称: 
1,3-Bis-(2,4,6-trimethylphenyl)imidazolinium chloride
N,N'-(2,4,6-Trimethylphenyl)dihydroimadazolium chloride
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B803097MACKLIN1,3 -双( 2,4,6 -三甲苯基)氯化咪唑鎓97%26元/200mg;   36元/1g;   120元/5g;   580元/25g;   2230元/100g;   展开
储存:室温
状态:白色到棕褐色粉末
B3158TCI1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride>98.0%(T)(HPLC)695元/1G;   1990元/5G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C21H27ClN2 = 342.91
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN7455488
PubChem物质ID87560276
MDL编号MFCD09039279

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

熔点286 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
07-4011Strem1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloridemin. 97%705元/500mg;   2100元/2g;   展开
C37833Alfa Aesar1,3-Bis(2,4,6-trimethylphenyl)imidazolidinium chloride97%1674元/1g;   7731元/5g;   展开

基本信息

Ref#
37833

MDL
09039279

分子式
C21 H27 Cl N2

分子量
342.91

656631Sigma-Aldrich1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride95%359.22元/1 G;   1020.86元/5 G;   展开

产品说明

一般描述

1,3-双(2,4,6-三甲基苯基)咪唑啉氯化物是一种 NHC(N-杂环卡宾)配体,其可与金属预催化剂结合形成具有高催化活性的络合物。

应用

N-杂环卡宾配体

N-杂环卡宾催化剂前体用于:

  • 叠氮化物与末端乙炔的区域选择性环加成反应,生成 1,4-二取代的三唑。内部乙炔也可与该催化剂一起使用。
  • Markovnikov 型末端炔烃的水合作用
  • 酮的氢化硅烷化和叠氮化物和炔烃的环加成
  • Suzuki-Miyaura 反应
  • 发光实验

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C21H27ClN2
分子量342.91
MDL编号MFCD09039279
PubChem化学物质编号24884213
NACRESNA.22

产品性质

质量水平100
测定95%
reaction suitabilityreagent type: ligand
mp280-286 ℃
SMILES string[Cl-].Cc1cc(C)c(N2CC[N+](=C2)c3c(C)cc(C)cc3C)c(C)c1
InChI1S/C21H27N2.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;/h9-13H,7-8H2,1-6H3;1H/q+1;/p-1
InChI keyCOGMCBFILULEOS-UHFFFAOYSA-M

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
036862Fluorochem1,3-Bis-(2,4,6-trimethylphenyl)imidazolidiniumchloride97%1342元/1g;   4664元/5g;   展开

基本信息

CAS Number173035-10-4
MDL NumberMFCD09039279
Melting Point286℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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