| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| C805688 | MACKLIN | 三(三苯基膦)羰基氢化铑(I) | Rh 11.2% | 361元/250mg; 685元/500mg; 1135元/1g; | 咨询 |
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| C1383 | TCI | Carbonylhydridotris(triphenylphosphine)rhodium(I) | | 1690元/1G; 5190元/5G; | 咨询 |
基本信息 | 分子式/分子量 | C55H46OP3Rh = 918.80 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气,湿气 (分解) | | PubChem物质ID | 87566394 | | SDBS (AIST Spectral DB) | 39303 | | Merck Index (14) | 9758 | | MDL编号 | MFCD00151644 |
技术规格 | Appearance | Light yellow to Yellow powder to crystal | | Elemental analysis(Carbon) | 70.50 to 72.60 % |
物性(参考值) | 熔点 | 122 ℃(dec.) | | 溶解性(可溶于) | 苯,二氯甲烷,氯仿 |
安全信息 | 危险性说明 | H413 : 可能对水生生物造成长期持续有害影响。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
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| 199224 | J&K | Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride | 98% | 532元/250MG; 2049元/1G; 8165元/5G; | 咨询 |
基本信息 | 分子式 | C55H46OP3Rh | | 分子量 | 918.79 | | 熔点 | 150 | | MDL编码 | MFCD00151644 | | Merck | 13,9827 | | EINECS 编号 | 241-230-3 |
安全信息 | 图形或危害标志 |   | | 提示语 | Danger | | 危险说明 | H301
H311
H331 | | 防范说明 | P261
P280
P301+P310
P311 | | UN号码 | 2811 | | 危险分类 | 6.1 | | 包装等级 | II | | WGK | 1 | | TSCA | 是 |
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| 45-0900 | Strem | Hydridocarbonyltris(triphenylphosphine)rhodium(I) | 98% | 1155元/250mg; 3435元/1g; 13725元/5g; | 咨询 |
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| 010016 | Alfa Aesar | Carbonylhydridotris(triphenylphosphine)rhodium(I) | Rh 10.0% min | 0元/0.1g; 0元/1g; 0元/5g; | 咨询 |
应用
Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation 基本信息 MDL
MFCD00151644 EINECS
241-230-3 分子式
C55H46OP3Rh 分子量
918.80 熔点
138° dec 密度
1.33 灵敏度
Moisture Sensitive. Ambient temperatures. 形态
Powder 溶解性
Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands Merck
14,9758 GHS危害和防范说明 Hazard Statements
H413
May cause long lasting harmful effects to aquatic life. 安全信息 危险等级
6.1 包装组
III 危险类别
53
May cause long-term adverse effects in the aquatic environment. 安全等级
60-61
This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets. TSCA
是 |
| 225665 | Sigma-Aldrich | Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride | 97% | 1254.98元/500 MG; 11922.4元/5 G; | 咨询 |
产品说明 包装 5 g in glass bottle
500 mg in amber glass bottle 应用 催化亚甲基环丙烷类化合物进行开环异构化反应，生成 1,3-二烯类化合物。 特点和优势 均相催化剂。 基本信息 | 线性分子式 | [(C6H5)3P]3Rh(CO)H | | 分子量 | 918.78 | | EC 号 | 241-230-3 | | MDL编号 | MFCD00151644 | | PubChem化学物质编号 | 24853512 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | reaction suitability | core: rhodium
reagent type: catalyst | | mp | 150 ℃ (dec.) (lit.) | | SMILES string | [RhH].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 | | InChI | 1S/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;; | | InChI key | AACIZACVKFEETJ-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects | | WGK | WGK 1 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges |
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| 048597 | Fluorochem | Carbonyltris(triphenylphosphine)rhodium(I)hydride | | 2442元/1g; 10560元/5g; | 咨询 |
基本信息 | CAS Number | 17185-29-4 | | MDL Number | MFCD00151644 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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