CAS 1714-29-0; 1-溴芘; 1-bromopyrene

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货号

品牌

产品名称

规格

包装、参考价格

B803421

MACKLIN

1-溴芘

96%

30元/1g; 67元/5g; 203元/25g; 722元/100g; 3463元/500g;

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储存：室温
状态：白色到黄色到棕褐色粉末,晶体或块状

B1495

TCI

1-Bromopyrene

>95.0%(GC)

295元/5G; 1190元/25G;

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基本信息

纯度/分析方法	>95.0%(GC)
分子式/分子量	C₁₆H₉Br = 281.15
外观与形状(20℃)	固体
Reaxys-RN	1912059
PubChem物质ID	87564408
SDBS (AIST Spectral DB)	11784
MDL编号	MFCD00015767

技术规格

Appearance	White to Orange to Green powder to crystal
Purity(GC)	min. 95.0 %
Melting point	95.0 to 102.0 ℃

物性(参考值)

熔点	98 ℃
沸点	255 ℃/7 mmHg
溶解性(可溶于)	二氯甲烷

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

340593

J&K

1-Bromopyrene

95%

117元/1G; 466元/5G; 1520元/25G;

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基本信息

分子式	C₁₆H₉Br
分子量	281.15
熔点	102-105
MDL编码	MFCD00015767

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

018280

Alfa Aesar

1-Bromopyrene

95%

916元/1g; 3759元/5g;

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应用
1-Bromopyrene is used in the cleavage of DNA in studies. It is also used in the preparation of DNA base analogs.

备注
Store at room temperature. Keep container tightly closed in a dry and well-ventilated and exhaust required. Store away from oxidizing agents.

基本信息

MDL
MFCD00015767

分子式
C₁₆H₉Br

分子量
281.13

熔点
94-95°

灵敏度
Ambient temperatures.

形态
Crystalline

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
否

391573

Sigma-Aldrich

1-Bromopyrene

96%

604.67元/1 G;

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产品说明

一般描述

1-溴芘是一种多环芳烃 (PAH) ，是一种单溴取代芘衍生物。其合成已有报道。其的高温气相紫外吸收光谱已经被研究。采用三重四极杆串联质谱和电子连接脱附化学电离质谱 (DCI-MS) 研究了 1-溴芘的亲合电子结构。参与合成含芘基团的新型钌 (II) 联吡啶或三吡啶配合物。用电子转移停流 (ETSF) 法分析了 1-溴芘阳离子自由基与水在乙腈中的反应。

应用

1-溴芘是用于比较一些芘衍生物的取代基在诱导人皮肤角质形成细胞的光毒性、DNA损伤和修复以及在甲醇中光诱导的脂质过氧化作用的比较研究的合适试剂。它是研究高温下PAHs的紫外光子辅助热分解研究的合适试剂。
1-溴芘可用作标准品，与基于芘的荧光探针的光谱属性进行比较。它可用于研究卤杂原子的加入对多环芳烃蒸汽压和热力学性质的影响。
可用于以下合成：

2-甲基-4-芘-1-基-丁-3-炔-2-醇
1-乙炔基芘
基于倍半硅氧烷 (SSQ) 的杂交
芘基团功能化钌纳米颗粒
一和二芘基全氟烷烃
寡聚(1-溴py)(OBrP)薄膜
二硝基芘衍生的 DNA 加合物

包装

1 g in glass bottle

基本信息

经验(实验)分子式	C₁₆H₉Br
分子量	281.15
MDL编号	MFCD00015767
PubChem化学物质编号	24864389
NACRES	NA.22

产品性质

质量水平	100
测定	96%
mp	102-105 ℃ (lit.)
SMILES string	Brc1ccc2ccc3cccc4ccc1c2c34
InChI	1S/C16H9Br/c17-14-9-7-12-5-4-10-2-1-3-11-6-8-13(14)16(12)15(10)11/h1-9H
InChI key	HYGLETVERPVXOS-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

903727

Amethyst

1-Bromopyrene

95%, 用于合成

65元/1G; 134元/5G; 463元/25G; 1521元/100G;

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基本信息

分子式	C₁₆H₉Br
分子量	281.15
熔点	102-105
MDL编码	MFCD00015767

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

037024

Fluorochem

1-Bromo-pyrene

97%

572元/1g; 1430元/5g; 3410元/25g; 10230元/100g;

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基本信息

CAS Number	1714-29-0
MDL Number	MFCD00015767
Boiling Point	255℃
Melting Point	95-102℃
Density	1.4316

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .