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CAS: 171364-80-0
分子式: C14H19BO4
分子量: 262.11
熔点: 77-81 °C(lit.)
中文名称: 
4-甲氧甲酰苯硼酸频哪醇酯
4-(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)苯甲酸甲酯
4-甲氧羰基本硼酸频那醇酯
英文名称: 
4-Methoxycarbonylphenylboronic acid pinacol ester
4-Carbomethoxyphenylboronic acid pinacol ester
4-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid methyl ester
推荐供应商
货号品牌产品名称规格包装、参考价格
M814077MACKLIN4-甲氧羰基苯硼酸频哪醇酯95%24元/1g;   56元/5g;   224元/25g;   764元/100g;   咨询
储存:室温
状态:白色到灰白色粉末或晶体
M3057TCIMethyl 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate>98.0%(GC)(T)135元/1G;   190元/5G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C14H19BO4 = 262.11
外观与形状(20℃)固体
Reaxys-RN7709458
PubChem物质ID354335088
MDL编号MFCD02179438

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point80.0 to 84.0 ℃

物性(参考值)

熔点82 ℃
H28942Alfa Aesar4-(Methoxycarbonyl)benzeneboronic acid pinacol ester97%1764元/1g;   4984元/5g;   咨询

基本信息

MDL
MFCD02179438

分子式
C14H19BO4

分子量
262.11

熔点
77-81°

形态
Crystalline powder

安全信息

TSCA
否

594768Sigma-Aldrich4-Methoxycarbonylphenylboronic acid pinacol ester97%735.57元/5 G;   咨询

产品说明

应用

4-Methoxycarbonylphenylboronic acid pinacol ester can be used as a reagent:   

  • In Suzuki–Miyaura cross-coupling reaction with aryl halides to form C-C bonds.     
  • For the synthesis of biphenyl derivatives by selective ortho C-H arylation of ketones using Rh catalyst.

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C14H19BO4
分子量262.11
MDL编号MFCD02179438
PubChem化学物质编号24881534
NACRESNA.22

产品性质

质量水平100
测定97%
mp77-81 ℃ (lit.)
SMILES stringCOC(=O)c1ccc(cc1)B2OC(C)(C)C(C)(C)O2
InChI1S/C14H19BO4/c1-13(2)14(3,4)19-15(18-13)11-8-6-10(7-9-11)12(16)17-5/h6-9H,1-5H3
InChI keyREIZEQZILPXYKS-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
010813FluorochemMethyl 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate97%352元/1g;   660元/5g;   1606元/25g;   咨询

基本信息

CAS Number171364-80-0
MDL NumberMFCD02179438

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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