CAS 16971-33-8; carbonylchlorohydridotris(triphenyl-phosphine)rut

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C805718

MACKLIN

羰基氯氢三(三苯基膦)钌(II)

97%

82元/1g; 378元/5g;

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储存：室温
状态：白色到黄色到灰色到棕色晶体或粉末

44-0085

Strem

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

99%

1170元/1g; 4620元/5g;

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Technical Notes:

1.Catalyst for alcohol a-allylation with dienes or allenes under transfer hydrogenation conditions.

2.Catalyst for tandem is omerization (to imine), followed by Friedel Crafts alkylation.

3.Catalyst for amination of alcohols with ammonia.

References:

1. J. Am. Chem. Soc., 2008, 130, 6338.

2.J. Am. Chem. Soc., 2011, 133, 1 141.

3.J. Am. Chem. Soc., 2008, 130, 14453

4.Angew. Chem. Int. Ed., 2011, 50, 7599.

044955

Alfa Aesar

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

1600元/1g; 6532元/5g; 27594元/25g;

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应用
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

备注
Store in cool place. Air, moisture, and light sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00049804

EINECS
241-051-0

分子式
C₅₅H₄₆ClOP₃Ru

分子量
952.41

熔点
204-206° dec.

灵敏度
Light Sensitive. Very Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Insoluble in water, ethanol, and DMSO. Sparingly soluble in benzene, chloroform and acetone.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

C39214

Alfa Aesar

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

2820元/1g; 11498元/5g;

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基本信息

Ref#
39214

MDL
49804

分子式
C55 H46 Cl O P3 Ru

分子量
952.4

形态
Crystalline

334995

Sigma-Aldrich

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

921.64元/1 G;

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基本信息

线性分子式	[(C₆H₅)₃P]₃Ru(CO)(Cl)H
分子量	952.40
EC 号	241-051-0
MDL编号	MFCD00049804
PubChem化学物质编号	24860276

产品性质

质量水平	100
reaction suitability	core: ruthenium reagent type: catalyst
mp	204-206 ℃ (dec.) (lit.)
SMILES string	Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.CO.ClH.Ru/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h31-15H;;1H;/q;;;;;+1/p-1
InChI key	MVJRXTSUBHUUPN-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315 - H319 - H335
预防措施声明	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves