[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 1671-87-0
关键词:       仅模糊查询
CAS: 1671-87-0
分子式: C12H8N6
分子量: 236.23
沸点: 509.1ºC at 760mmHg
熔点: 225ºC
英文名称: 
3,6-di-2-pyridyl-1,2,4,5-tetrazine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D823734MACKLIN3,6-二(2-吡啶基)-1,2,4,5-四嗪98%28元/1g;   75元/5g;   263元/25g;   787元/100g;   2950元/500g;   展开
储存:室温
状态:红色到暗红色到棕色粉末到晶体
折射率:1.632
D3640TCI3,6-Di(2-pyridyl)-1,2,4,5-tetrazine>98.0%(HPLC)525元/1G;   1930元/5G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C12H8N6 = 236.24
外观与形状(20℃)固体
Reaxys-RN405091
PubChem物质ID87560390
MDL编号MFCD00121717

技术规格

AppearanceRed to Dark red to Brown powder to crystal
Purity(HPLC)min. 98.0 area%

物性(参考值)

熔点225 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
321216J&K3,6-Di-2-pyridyl-1,2,4,5-tetrazine98%461元/1G;   1590元/5G;   展开

基本信息

分子式C12H8N6
分子量236.24
熔点225
MDL编码MFCD00121717

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
H53484Alfa Aesar3,6-Di-2-pyridyl-1,2,4,5-tetrazine96%1118元/1g;   4818元/5g;   16675元/25g;   展开

应用
3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. It also may be used in the synthesis of novel cyclic tetranuclear ZnII complex and synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00121717

分子式
C12H8N6

分子量
236.24

熔点
225° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

403547Sigma-Aldrich3,6-Di-2-pyridyl-1,2,4,5-tetrazine96%684.69元/1 G;   955.82元/5 G;   展开

产品说明

一般描述

通过高速振动铣削技术,3,6-二-2-吡啶基-1,2,4,5-四嗪可与富勒烯C60发生固态反应。 它在逆电子需求Diels Alder反应中充当缺电子二烯。
3,6-二-2-吡啶基-1,2,4,5-四嗪(DPTZ)与CuSO4·6H2O和Cu(Ac)2·H2O进行溶剂热反应可生成含铜配位聚合物。 它能与吗啉的烯胺衍生物和5-、6-、7-和8-元环酮反应,得到哒嗪衍生物。

应用

3,6-二-2-吡啶基-1,2,4,5-四嗪可用于以下研究:

  • 通过金属辅助水解,制备单核、环状四核和1-D螺旋链Cu(II)络合物。
  • 新型环状四核ZnII复合物的合成。
  • 通过与烯烃或炔烃的逆电子需求Diels Alder反应,合成取代的3,6-二(2-吡啶基)哒嗪。

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C12H8N6
分子量236.23
MDL编号MFCD00121717
PubChem化学物质编号24865200
NACRESNA.22

产品性质

质量水平100
测定96%
mp225 ℃ (dec.) (lit.)
SMILES stringc1ccc(nc1)-c2nnc(nn2)-c3ccccn3
InChI1S/C12H8N6/c1-3-7-13-9(5-1)11-15-17-12(18-16-11)10-6-2-4-8-14-10/h1-8H
InChI keyJFBIRMIEJBPDTQ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
211605Fluorochem3,6-Di(pyridin-2-yl)-1,2,4,5-tetrazine96%330元/1g;   1188元/5g;   4180元/25g;   展开

基本信息

CAS Number1671-87-0
MDL NumberMFCD00121717

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9