| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| B801885 | MACKLIN | 1,2-双(二苯基膦)乙烷 | 98% | 27元/1g; 30元/5g; 55元/25g; 195元/100g; 881元/500g; | 展开 |
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| B1137 | TCI | 1,2-Bis(diphenylphosphino)ethane | >97.0%(GC)(T) | 495元/10G; 995元/25G; | 展开 |
基本信息 | 纯度/分析方法 | >97.0%(GC)(T) | | 分子式/分子量 | C26H24P2 = 398.43 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 761261 | | PubChem物质ID | 87564079 | | SDBS (AIST Spectral DB) | 14 | | MDL编号 | MFCD00003047 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(GC) | min. 97.0 % | | Purity(Iodometric Titration) | min. 97.0 % | | Melting point | 137.0 to 144.0 ℃ |
物性(参考值) |
| 190390 | J&K | 1,2-Bis(diphenylphosphino)ethane | 98% | 203元/5G; 629元/25G; 2148元/100G; | 展开 |
基本信息 | 分子式 | C26H24P2 | | 分子量 | 398.42 | | 熔点 | 137-142 | | MDL编码 | MFCD00003047 | | Beilstein | 761261 | | EINECS 编号 | 216-769-2 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 |  | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P280
P302+P352
P305+P351+P338 | | WGK | 3 | | TSCA | 是 |
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| 15-0200 | Strem | 1,2-Bis(diphenylphosphino)ethane | 99% | 459元/5g; 1501元/25g; 4476元/100g; | 展开 |
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| A11419 | Alfa Aesar | 1,2-Bis(diphenylphosphino)ethane | 97+% | 798元/5g; 2324元/25g; 5016元/100g; | 展开 |
应用
1,2-Bis(diphenylphosphino)ethane is a bidendate ligand used in coordination chemistry to prepare metal complexes. It is involved in the metal-catalyzed allylic alkylation and decarboxylation of allylic esters. It is also used in 1,3-diene synthesis. Further, it is used in cycloaddition reactions and carbonylation reactions. In addition to this, it is used to prepare bis(dicyclohexylphosphino)ethane by hydrogenation. 备注
Air sensitive. Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00003047 EINECS
216-769-2 分子式
C26H24P2 分子量
398.42 熔点
138-143° 灵敏度
Air Sensitive. Store under Argon. Ambient temperatures. 形态
Crystalline powder 溶解性
Soluble in acetone, methanol and alcoholic hydrochloric acid. Beilstein
761261 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
是 |
| C14791 | Alfa Aesar | 1,2-Bis(diphenylphosphino)ethane | 98+% | 546元/1g; 806元/10g; 2703元/50g; 11558元/250g; | 展开 |
基本信息 Ref#
14791 MDL
3047 分子式
C26 H24 P2 分子量
398.41 |
| 376728 | Sigma-Aldrich | Ethylenebis(diphenylphosphine) | 99% | 149.43元/1 G; 469.72元/5 G; | 展开 |
产品说明 包装 1, 5 g in glass bottle 应用 金属催化烯丙基烷基化的配体；烯丙基酯的脱羧；1，3-二烯合成；环加成反应；羰基化反应。 基本信息 | 线性分子式 | (C6H5)2PCH2CH2P(C6H5)2 | | 分子量 | 398.42 | | Beilstein | 761261 | | EC 号 | 216-769-2 | | MDL编号 | MFCD00003047 | | PubChem化学物质编号 | 24863460 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 99% | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | | mp | 137-142 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4 | | InChI | 1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2 | | InChI key | QFMZQPDHXULLKC-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H335 | | 预防措施声明 | P261 - P271 - P304 + P340 + P312 - P403 + P233 - P405 - P501 | | 危险分类 | STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 106496 | Sigma-Aldrich | Ethylenebis(diphenylphosphine) | 97% | 538.19元/10 G; 1438.39元/50 G; | 展开 |
产品说明 应用 用于获得混合金属簇。
Ligand for metal-catalyzed allylic alkylation; decarboxylation of allylic esters; 1,3-diene synthesis; cycloaddition reactions; carbonylation reactions. 包装 10, 50 g in glass bottle 基本信息 | 线性分子式 | (C6H5)2PCH2CH2P(C6H5)2 | | 分子量 | 398.42 | | Beilstein | 761261 | | EC 号 | 216-769-2 | | MDL编号 | MFCD00003047 | | PubChem化学物质编号 | 24846735 |
产品性质 | 质量水平 | 200 | | 测定 | 97% | | reaction suitability | reagent type: ligand
reaction type: C-C Bond Formation
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Cycloadditions
reagent type: ligand
reaction type: Decarboxylations
reagent type: ligand
reaction type: Diels-Alder Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling | | mp | 137-142 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4 | | InChI | 1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2 | | InChI key | QFMZQPDHXULLKC-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H335 | | 预防措施声明 | P261 - P271 - P304 + P340 + P312 - P403 + P233 - P405 - P501 | | 危险分类 | STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 148746 | Amethyst | 1,2-Bis(diphenylphosphino)ethane | 98%, 用于合成 | 40元/5G; 99元/25G; 286元/100G; | 展开 |
基本信息 | 分子式 | C26H24P2 | | 分子量 | 398.42 | | 熔点 | 137-142 | | MDL编码 | MFCD00003047 | | Beilstein | 761261 | | EINECS 编号 | 216-769-2 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P280
P302+P352
P305+P351+P338 | | WGK | 3 | | TSCA | 是 |
|
| 050106 | Fluorochem | 1,2-Bis(diphenylphosphino)ethane | 95% | 352元/5g; 616元/10g; 3344元/100g; | 展开 |
基本信息 | CAS Number | 1663-45-2 | | MDL Number | MFCD00003047 | | Melting Point | 143-145℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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