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CAS: 164014-95-3
分子式: C8H9BO4
分子量: 179.96
中文名称: 
苯并-1,4-二氧六环-6-硼酸
3,4-(亚乙二氧基)苯硼酸
英文名称: 
(2,3-dihydro-1,4-benzodioxin-6-yl)-boronic acid
1,4-Benzodioxane-6-boronic acid
3,4-(Ethylenedioxy)benzeneboronic acid
1,4-Benzodioxan-6-boronic acid
推荐供应商
货号品牌产品名称规格包装、参考价格
B832843MACKLIN苯并-1,4-二氧六环-6-硼酸97%24元/250mg;   38元/1g;   157元/5g;   769元/25g;   咨询
储存:室温,干燥,密封
状态:白色到淡黄色到棕色固体
B4181TCI1,4-Benzodioxane-6-boronic Acid (contains varying amounts of Anhydride)950元/1G;   咨询

基本信息

分子式/分子量C8H9BO4 = 179.97
外观与形状(20℃)固体
Reaxys-RN7478648
PubChem物质ID253661132
MDL编号MFCD01009696

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(Neutralization titration)97.0 to 112.0 %

物性(参考值)

熔点118 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
243572J&K1,4-Benzodioxane-6-boronic acid97%528元/1G;   1629元/5G;   咨询

基本信息

分子式C8H9BO4
分子量179.97
MDL编码MFCD01009696
Beilstein7478648

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
L20296Alfa Aesar1,4-Benzodioxane-6-boronic acid97%1564元/1g;   5613元/5g;   咨询

基本信息

MDL
MFCD01009696

分子式
C8H9BO4

分子量
179.97

形态
Crystalline powder

Beilstein
7478648

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

635995Sigma-Aldrich1,4-Benzodioxane-6-boronic acid≥95%310.35元/1 G;   914.97元/5 G;   咨询

产品说明

应用

反应物参与到:

  • 与 1,8-萘啶 N -氧化物的加成反应
  • 碘环化和钯催化偶联反应合成吡喃喹啉
  • 合成 combretastatin 类似物的 Suzuki 偶联反应
  • Suzuki-Miyaura 偶联反应合成芳基取代的恶苯吲哚类化合物
  • 钯催化的Heck反应中间体的氧芳基化反应
  • 醌的 C-H 功能化

包装

1, 5 g in glass bottle

其他说明

含不定量的酸酐

基本信息

经验(实验)分子式C8H9BO4
分子量179.97
MDL编号MFCD01009696
PubChem化学物质编号24882748
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式powder
SMILES stringOB(O)c1ccc2OCCOc2c1
InChI1S/C8H9BO4/c10-9(11)6-1-2-7-8(5-6)13-4-3-12-7/h1-2,5,10-11H,3-4H2
InChI keySQDUGGGBJXULJR-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
016099Fluorochem1,4-Benzodioxane-6-boronic acid97%594元/1g;   1056元/5g;   3520元/25g;   咨询

基本信息

CAS Number164014-95-3
MDL NumberMFCD01009696
Melting Point116 - 118 ℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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