CAS 162291-02-3; (S)-(+)-1-[(R)-2-(diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine

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货号

品牌

产品名称

规格

包装、参考价格

S835563

MACKLIN

(S)-(+)-1-[(R)-2-(二苯基膦)二茂铁]乙基二环己基膦

97%

86元/100mg; 343元/500mg; 525元/1g; 2308元/5g;

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储存：室温
状态：暗橙色粉末

26-1211

Strem

(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct

min. 97%

1168元/100mg; 4410元/500mg; 13950元/2g; 52260元/10g;

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Technical Notes:

1. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products 1,2. These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, ß-ketoesters and simple alkenes

2. Pd-catalyzed, enantioselective, intramolecular a-substituted cyclic ketones: facile synthesis of functionalized chiral spirobicycles.

3.Asymmetric boron conjugate addition of a,ß-unsaturated carbonyl compounds catalyzed by CuOTf/Josiphos under non-alkaline conditions

4.Chiral amides via copper cata lyzed enantioselective conjugate additicon 5. Ruthenium-catalyzed enantioselective synthesis of ß-amino alcohols from 1,2-diols by "borrowing hydrogen". 6.Cobalt catalyzed asymmetric addition of silylacetylenes to 1, 1-disubstituted allenes. 7.L igand for Catalytic Asymmetric Synthesis of Phosphine Boronates . 8. Ligand for Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Cu-Catalyzed 1 ,6-Boration.

Y10330

Alfa Aesar

(2S)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphos

919元/100mg;

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基本信息

分子量
594.53

88718

Sigma-Aldrich

(S)-1-[(R_P)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

≥97%

988.82元/100 MG; 6851.74元/1 G; 129845元/50 G; 216453元/100 G;

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产品说明

一般描述

与 Solvias AG 合作销售

包装

1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

基本信息

经验(实验)分子式	C₃₆H₄₄FeP₂ · C₂H₅OH
分子量	640.60
MDL编号	MFCD00800285
PubChem化学物质编号	24888986
NACRES	NA.22

产品性质

描述	ethanol adduct
质量水平	100
测定	≥97%
光学纯度	ee: ≥99%
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C5CCCCC5)C6CCCCC6
InChI	1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m0../s1
InChI key	HGTBZFMPHBAUCQ-WLOLSGMKSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)