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CAS: 16182-04-0
分子式: C4H5NO2S
分子量: 131.15
沸点: 56℃(18 t
中文名称: 
异硫氰酰甲酸乙酯
英文名称: 
ethoxycarbonyl isothiocyanate
Ethyl isothiocyanatoformate
Isothiocyanatoformic Acid Ethyl Ester
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货号品牌产品名称规格包装、参考价格
E823976MACKLIN乙氧羰基异硫氰酸酯98%73元/5g;   226元/25g;   674元/100g;   2500元/500g;   咨询
储存:2~8°C,干燥
状态:无色到黄色到橙色液体
折射率:n20/D 1.500(lit.)
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储存:2~8°C,干燥
状态:无色到黄色到橙色液体
折射率:n20/D 1.500(lit.)
E0440TCIEthoxycarbonyl Isothiocyanate>95.0%(GC)420元/5G;   1470元/25G;   咨询

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C4H5NO2S = 131.15
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN606091
PubChem物质ID87569695
SDBS (AIST Spectral DB)13174
MDL编号MFCD00004814

技术规格

AppearanceLight yellow to Brown clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点61 ℃/6 mmHg
闪点50 ℃
比重1.16
折射率1.50

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H331 : 吞咽或吸入可致中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H334 : 吸入可能导致过敏或哮喘病症状或呼吸困难。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P342 + P311 : 如有呼吸系统病症:呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

运输信息

UN编号UN1992
类别3 / 6.1
包装类别 III
监管条件代码(*)
314456J&KEthoxycarbonyl Isothiocyanate98%439元/5G;   1317元/25G;   咨询

基本信息

分子式C4H5NO2S
分子量131.15
沸点56
闪点50
密度1.112
折光率(n20D)1.5000
MDL编码MFCD00004814
Beilstein606091
EINECS 编号240-318-9
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H315
H317
H319
H331
H334
H335
防范说明P261
P280
P305+P351+P338
P311
UN号码2929
危险分类6.1
次要危险性3
包装等级II
WGK3
L00911Alfa AesarEthoxycarbonyl Isothiocyanate97%1035元/5g;   3504元/25g;   咨询

应用
Ethoxycarbonyl isothiocyanate, is used as a building block in the synthesis of various heterocycles. It is also used for the synthesis of 1,2,4-oxadiazolidine-3,5-dione. It is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

备注
Moisture, Heat Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

基本信息

MDL
MFCD00004814

EINECS
240-318-9

分子式
C4H5NO2S

分子量
131.15

沸点
44-46°/10mm

闪点
50°(122°F)

密度
1.110

折射率
1.5030

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Liquid

溶解性
Soluble in chloroform and ether.

Beilstein
606091

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H331-H315-H319-H334-H335
Flammable liquid and vapour.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause respiratory irritation.

Precautionary Statements
P210-P284-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear respiratory protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
10-23-36/37/38-42
Flammable.Toxic by inhalation.Irritating to eyes, respiratory system and skin.May cause sensitization by inhalation.

安全等级
4-9-20-23-26-36/37/39-45-60
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

TSCA
否

196126Sigma-AldrichEthoxycarbonyl Isothiocyanate98%717元/5 G;   2084.91元/25 G;   咨询

产品说明

一般描述

Ethoxycarbonyl isothiocyanate reacts with 2-amino-tetrahydrobenzo[b]thiophene derivatives to yield tetrahydrobenzo[b]thiophen-2-thiourea derivatives.

应用

用于以甲锡烷基芳烃合成硫脲的通用试剂,从 2-氨基-2-噁唑啉制备 1,3,5-三嗪-2-酮-4-硫酮,以及用氨基脱氧糖合成 N-酰基硫脲。

包装

5, 25 g in glass bottle

基本信息

线性分子式SCNCOOCH2CH3
分子量131.15
Beilstein606091
EC 号240-318-9
MDL编号MFCD00004814
PubChem化学物质编号24851737

产品性质

质量水平100
测定98%
形式liquid
折射率n20/D 1.500 (lit.)
bp56 ℃/18 mmHg (lit.)
密度1.112 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringCCOC(=O)N=C=S
InChI1S/C4H5NO2S/c1-2-7-4(6)5-3-8/h2H2,1H3
InChI keyBDTDECDAHYOJRO-UHFFFAOYSA-N

安全信息

象形图GHS02GHS06GHS08
警示用语:Danger
危险声明H226 - H315 - H317 - H319 - H331 - H334 - H335
预防措施声明P210 - P280 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338
危险分类Acute Tox. 3 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官Respiratory system
储存分类代码3 - Flammable liquids
WGKWGK 3
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
002560FluorochemEthoxycarbonyl Isothiocyanate98%264元/1g;   528元/5g;   1386元/25g;   4092元/100g;   咨询

基本信息

CAS Number16182-04-0
MDL NumberMFCD00004814
Boiling Point56℃/18mm
Density1.112

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P285: In case of inadequate ventilation wear respiratory protection.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 + P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2, dry powder or foam for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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