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CAS: 1615-02-7
分子式: C9H7ClO2
分子量: 182.60
熔点: 246-250℃
中文名称: 
4-氯苯乙烯酸
对氯肉桂酸
对氯苯丙烯酸
4-氯肉桂酸
英文名称: 
trans-3-(4-Chlorophenyl)propenoic acid
4-Chlorocinnamic acid,predominantly trans
p-chloro-cinnamic aci
3-(4-chlorophenyl)-2-propenoic aci
3-(4-chlorophenyl)-2-propenoic acid
3-(p-chlorophenyl)acrylic acid
4-chlorocinnamic acid
p-chlorocinnamic acid
β-(p-Chlorophenyl)-acrylic acid
2-Propenoic acid,3-(4-chlorophenyl)-
性质描述: 无色结晶。有顺式和反式两种。溶于乙醇,顺式熔点110.5℃,反式熔点249-250℃。
生产方法: 由对氯苯甲醛与乙酐反应而得。将对氯苯甲醛、乙酐和乙酸钠在一起在180℃下反应13h。反应毕,稍冷,倒入水中,过滤,用水洗涤滤饼,用氨水反复溶解,至仅残留少量棕黄色粘稠状物为止。将所得铵盐溶液过滤,用3N稀硫酸将对氯肉桂酸重新析出,经过滤干燥得产品。产率约为80%。
用途: 有机合成中间体,用于合成对氯苯丙酸,生产除草剂麦敌散。
推荐供应商
货号品牌产品名称规格包装、参考价格
C804207MACKLIN4-氯肉桂酸99%29元/5g;   47元/25g;   93元/100g;   325元/500g;   1554元/2.5kg;   咨询
储存:室温
状态:白色结晶粉末
C0149TCI4-Chlorocinnamic Acid>98.0%(GC)(T)100元/25G;   1590元/500G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H7ClO2 = 182.60
外观与形状(20℃)固体
Reaxys-RN2044025
PubChem物质ID87565326
SDBS (AIST Spectral DB)7937
MDL编号MFCD00004396

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#GD8490000
173166J&K4-Chlorocinnamic Acid99%60元/5G;   193元/25G;   635元/100G;   2535元/500G;   咨询

基本信息

分子式C9H7ClO2
分子量182.61
熔点248-250
MDL编码MFCD00004396
Beilstein2044025
EINECS 编号216-564-8

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P262
WGK3
RTECSGD8490000
TSCA否
A15304Alfa Aesar4-Chlorocinnamic Acidpredominantly trans, 99%1198元/25g;   3414元/100g;   14556元/500g;   咨询

基本信息

MDL
MFCD00004396

EINECS
216-564-8

分子式
C9H7ClO2

分子量
182.61

熔点
248-253°

形态
Crystalline powder

Beilstein
1365308

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
GD8490000

TSCA
否

C10894Alfa Aesar4-Chlorocinnamic Acid99%, predominantly trans891元/25g;   2946元/100g;   咨询

基本信息

Ref#
10894

MDL
4396

分子式
C9 H7 Cl O2

分子量
182.61

形态
White cryst powder

C31600Sigma-Aldrich4-Chlorocinnamic Acid99%482.17元/25 G;   咨询

基本信息

线性分子式ClC6H4CH=CHCO2H
分子量182.60
Beilstein2044025
EC 号216-564-8
MDL编号MFCD00004396
PubChem化学物质编号24892589
NACRESNA.22

产品性质

质量水平100
测定99%
mp248-250 ℃ (lit.)
SMILES stringOC(=O)\C=C\c1ccc(Cl)cc1
InChI1S/C9H7ClO2/c10-8-4-1-7(2-5-8)3-6-9(11)12/h1-6H,(H,11,12)/b6-3+
InChI keyGXLIFJYFGMHYDY-ZZXKWVIFSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
319331Fluorochem3-(4-Chlorophenyl)acrylic acid98%242元/5g;   484元/25g;   1320元/100g;   咨询

基本信息

CAS Number1615-02-7
MDL NumberMFCD00004396
Melting Point246-252℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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