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CAS: 16116-78-2
分子式: C11H13BrSi
分子量: 253.21
熔点: 61-63°C (Lit.)
英文名称: 
(4-BROMOPHENYLETHYNYL)TRIMETHYLSILANE
推荐供应商
货号品牌产品名称规格包装、参考价格
B838613MACKLIN(4-溴苯基乙炔基)三甲基硅烷98%31元/1g;   99元/5g;   469元/25g;   1870元/100g;   咨询
储存:室温
状态:白色到黄色固体
B6028TCI(4-Bromophenylethynyl)trimethylsilane180元/1G;   640元/5G;   咨询

基本信息

分子式/分子量C11H13BrSi = 253.21
外观与形状(20℃)固体
Reaxys-RN2830864
MDL编号MFCD01863556

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Melting point60.0 to 64.0 ℃

物性(参考值)

熔点62 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
H55534Alfa Aesar(4-Bromophenylethynyl)trimethylsilane98%536元/1g;   2674元/5g;   13372元/25g;   咨询

应用
It is used as the intermediate of Organic Light Emitting Diode (OLED).

备注
Store at room temperature. Avoid strong oxidizing agents.

基本信息

MDL
MFCD01863556

分子式
C11H13BrSi

分子量
253.21

熔点
61-63°

灵敏度
Ambient temperatures.

形态
Powder

安全信息

TSCA
否

494011Sigma-Aldrich(4-Bromophenylethynyl)trimethylsilane98%369.09元/5 G;   1370.46元/25 G;   咨询

产品说明

一般描述

(4-Bromophenylethynyl)trimethylsilane can be synthesized by the palladium catalyzed reaction between 4-bromo-1-iodobenzene and trimethylsilylacetylene. It undergoes Buchwald-Hartwig coupling with para-substituted diphenylamines.

应用

(4-Bromophenylethynyl)trimethylsilane may be used to synthesize:

  • 1-bromo-4-ethynylbenzene
  • 4-(4-bromophenyl)-3-butyn-2-one
  • 4-ethynyl-4′-tert-butylbiphenyl
  • 1,4-bis[2-(4-bromophenyl)ethynyl]-2,5-dihexylbenzene

包装

5, 25 g in glass bottle

基本信息

线性分子式BrC6H4C≡CSi(CH3)3
分子量253.21
MDL编号MFCD01863556
PubChem化学物质编号24872871

产品性质

质量水平100
测定98%
mp61-63 ℃ (lit.)
SMILES stringC[Si](C)(C)C#Cc1ccc(Br)cc1
InChI1S/C11H13BrSi/c1-13(2,3)9-8-10-4-6-11(12)7-5-10/h4-7H,1-3H3
InChI keyRNMSGCJGNJYDNS-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
239153Fluorochem((4-Bromophenyl)ethynyl)trimethylsilane95%242元/1g;   814元/5g;   1386元/10g;   3432元/25g;   咨询

基本信息

CAS Number16116-78-2
MDL NumberMFCD01863556
Melting Point61-63℃
Density1.192

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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