CAS 1608-26-0; 六甲基三氨基膦; Phosphorous triamide,hexamethyl-

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货号

品牌

产品名称

规格

包装、参考价格

T820304

MACKLIN

三(二甲胺基)膦

97%

30元/1g; 68元/5g; 309元/25g; 997元/100g;

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储存：室温
状态：无色液体
折射率：n20/D 1.463(lit.)

T1317

TCI

Tris(dimethylamino)phosphine (may contain precipitate)

>96.0%(GC)

990元/25ML;

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基本信息

纯度/分析方法	>96.0%(GC)
分子式/分子量	C₆H₁₈N₃P = 163.20
外观与形状(20℃)	液体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,湿气 (分解),加热
Reaxys-RN	906778
PubChem物质ID	87577088
SDBS (AIST Spectral DB)	13277
MDL编号	MFCD00008301

技术规格

Appearance	Colorless to Light yellow to Light orange clear liquid
Purity(GC)	min. 96.0 %

物性(参考值)

沸点	163 ℃
闪点	26 ℃
比重	0.90
折射率	1.46

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#

TH3390000

运输信息

UN编号	UN1993
类别	3
包装类别	III
监管条件代码(*)

15-7800

Strem

Tris(dimethylamino)phosphine

min. 98%

360元/1g; 667元/5g;

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A12571

Alfa Aesar

Hexamethylphosphorous triamide

97%

568元/5g; 1024元/10g; 1842元/25g; 3134元/50g; 15012元/250g;

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应用
Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00008301

EINECS
216-534-4

分子式
[(CH₃)₂N]₃P

分子量
163.21

熔点
-44°

沸点
162-164°

闪点
37°(98°F)

密度
0.898

折射率
1.4650

灵敏度
Air Sensitive. Store under Nitrogen. May form a Precipitate. Ambient temperatures.

形态
Liquid

溶解性
Miscible with water.

Beilstein
906778

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H340-H350
Flammable liquid and vapour.May cause genetic defects.May cause cancer.

Precautionary Statements
P210-P201-P280-P303+P361+P353-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
45-46-10
May cause cancer.May cause heritable genetic damage.Flammable.

安全等级
53-45
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
TH3390000

TSCA
是

C16248

Alfa Aesar

Hexamethylphosphorous triamide

97%

1400元/10ml; 4363元/50ml; 8134元/100ml;

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基本信息

Ref#
16248

MDL
8301

分子式
C6 H18 N3 P

分子量
163.2

闪点
26

密度
0.89

安全信息

危险等级
3

包装组
III

944510

Amethyst

Hexamethylphosphorous triamide

98%, 用于合成

113元/5G; 1334元/100G;

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基本信息

分子式	C₆H₁₈N₃P
分子量	163.20
熔点	-44
沸点	48-50
闪点	27
密度	0.898
折光率(n20D)	1.464 - 1.467
MDL编码	MFCD00008301
Beilstein	906778
EINECS 编号	216-534-4
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H340 H350
防范说明	P201 P308+P313 P370+P378 P403+P235
UN号码	1993
危险分类	3
包装等级	III
WGK	3
RTECS	TH3390000
TSCA	是

386689

Fluorochem

Hexamethylphosphorous triamide

95%

242元/1g; 704元/5g; 1870元/25ml; 5368元/100g;

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基本信息

CAS Number	1608-26-0
MDL Number	MFCD00008301
Density	0.898

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H302: Harmful if swallowed. H312: Harmful in contact with skin. H332: Harmful if inhaled.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P322: Specific measures (see . on this label). P330: Rinse mouth. P363: Wash contaminated clothing before reuse. P370 + P378: In case of fire: Use CO2, foam or extinguishing powder for extinction. P403 + P235: Store in a well-ventilated place. Keep cool. P501: Dispose of contents/container to local regulations.