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CAS: 16029-98-4
分子式: C3H9ISi
分子量: 200.09
沸点: 106℃
中文名称: 
三甲基硅基化碘
碘化三甲基硅烷
三甲基碘硅烷
英文名称: 
iodo-trimethyl-silane
Silane,iodotrimethyl-
trimethyliodosilane
trimethyliodosilane(tmis)
Trimethylsilyl iodide
iodotrimethyl-silan
iodotrimethylsilane
性质描述: 可燃液体。沸点106-108℃,相对密度(20/4℃)1.41。
生产方法: 将5.6g(0.21mol)铝粉和16.2g(0.10mol)六甲基二硅氧烷加入反应器,用氮气置换空气。加热至60℃,搅拌下加入50.8g(0.2mol)碘,升温至140℃回流1.5h。常压蒸馏,得32.6-35.3g三甲基碘硅烷,收率82-88%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
I811583MACKLIN三甲基碘硅烷97%,含铜作稳定剂30元/5g;   72元/25g;   227元/100g;   944元/500g;   1781元/1kg;   展开
储存:−20°C, 惰性气体保存, 易燃物区域, 避光, 干燥, 密封
状态:无色至黄色至橙色至红色至棕色液体
折射率:n20/D 1.471(lit.)
969218J&KIodotrimethylsilane, 1.0 M solution in methylene chloride1.0 M 二氯甲烷溶液133元/25ML;   528元/100ML;   展开

基本信息

分子式C3H9ISi
分子量200.09
沸点106
闪点-31
密度1.334
折光率(n20D)1.4330
MDL编码MFCD00001028
Beilstein1731136
EINECS 编号240-171-0
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H225
H314
H351
防范说明P210
P280
P305+P351+P338
P310
UN号码3286
危险分类3
次要危险性6.1,8
包装等级II
WGK3
TSCA
A12902Alfa AesarIodotrimethylsilane97%, stab. with copper310元/5g;   1055元/25g;   3447元/100g;   6894元/250g;   展开

应用
Iodotrimethylsilane is used for the introduction of trimethylsilyl group in organic synthesis. It is also useful for gas chromatography analysis by converting alcohol into a silyl ether derivative, thereby making it more volatile than the original molecule.

备注
Moisture and light Sensitive. Incompatible withstrong acids, strong bases, strong oxidizing agents and reacts violently with water.

基本信息

MDL
MFCD00001028

EINECS
240-171-0

分子式
C3H9ISi

分子量
200.09

沸点
105-106°

闪点
-2°(28°F)

密度
1.440

折射率
1.4760

灵敏度
Store at -20°C. Moisture Sensitive. Light Sensitive. Store under Nitrogen.

形态
Liquid

溶解性
Miscible with water.

Beilstein
1731136

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H314-H318
Highly flammable liquid and vapour.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
II

危险类别
11-14-34
Highly flammable.Reacts violently with water.Causes burns.

安全等级
8-9-16-23-26-36/37/39-45-60
Keep container dry.Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C18749Alfa AesarIodotrimethylsilane95-97%, stabilized818元/5ml;   1660元/25ml;   5491元/100ml;   10965元/250ml;   展开

基本信息

Ref#
18749

MDL
1028

分子式
C3 H9 I Si

分子量
200.1

闪点
-31

密度
1.4

形态
Liquid

安全信息

危险等级
3

包装组
II

S19550FluorochemTrimethylsilyl iodide98%484元/25g;   1210元/100g;   展开

基本信息

CAS Number16029-98-4
MDL NumberMFCD00001028
Boiling Point107℃
Density1.41

安全信息

图形或危害标志
危险性说明 EUH014: Reacts violently with water.
H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof / equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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