CAS 1594112-85-2; <i>trans</i>-bis(tricyclopentylphosphine)(2-methylphenyl)nickel(ii) chloride

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CAS:

1594112-85-2

英文名称:

trans-bis(tricyclopentylphosphine)(2-methylphenyl)nickel(ii) chloride

trans-(pcyp₃)₂ni(o-tolyl)cl

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货号

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产品名称

规格

包装、参考价格

901117

Sigma-Aldrich

trans-Bis(tricyclopentylphosphine)(2-methylphenyl)nickel(II) chloride

793.35元/100 MG;

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产品说明

应用

The following Ni complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他说明

Technology Spotlight: Jamison Nickel (II) Precatalysts
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式	C₃₇H₆₁ClNiP₂
分子量	661.97

产品性质

质量水平	100
形式	powder or solid
reaction suitability	core: nickel reagent type: catalyst
mp	156-161 ℃
SMILES string	CC1=[C-]C=CC=C1.P(C2CCCC2)(C3CCCC3)C4CCCC4.P(C5CCCC5)(C6CCCC6)C7CCCC7.[Ni+2].[Cl-]

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

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