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CAS: 15933-59-2
分子式: C4H15NSi2
分子量: 133.34
沸点: 99-100℃
熔点: 99-100°C (Lit.)
中文名称: 
1,1,3,3-四甲基二硅氮烷
四甲基二硅氮烷
英文名称: 
Silanamine,N-(dimethylsilyl)-1,1-dimethyl-
N-(dimethylsilyl)-1,1-dimethyl-Silanamine
Tetramethyldisilazane
n-(dimethylsilyl)-1,1-dimethyl-silanamin
1,1,3,3-tetramethyldisilazane
TMDS
Bis(dimethylsilyl)amine
Bisdimethylsilylamine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T833851MACKLIN四甲基二硅氮烷95%78元/5ml;   348元/25ml;   1278元/100ml;   展开
储存:2~8℃,Seal
状态:澄清液体
T0833TCI1,1,3,3-Tetramethyldisilazane>97.0%(GC)490元/5ML;   1540元/25ML;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C4H15NSi2 = 133.34
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN741869
PubChem物质ID87576669
SDBS (AIST Spectral DB)4171
MDL编号MFCD00025626

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点100 ℃
闪点-8 ℃
比重0.77
折射率1.41

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H225 : 高度易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

运输信息

UN编号UN2924
类别3 / 8
包装类别 II
监管条件代码(*)
585626J&K1,1,3,3-Tetramethyldisilazane97%399元/5ML;   1283元/25ML;   展开

基本信息

分子式C4H15NSi2
分子量133.34
沸点99-100
闪点-3
密度0.752
折光率(n20D)1.4040
MDL编码MFCD00025626
Beilstein741869
EINECS 编号240-072-2

安全信息

图形或危害标志
提示语Danger
危险说明H225
H315
H319
H335
防范说明P210
P261
P305+P351+P338
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK3
TSCA
A14304Alfa AesarTetramethyldisilazane97%1446元/10g;   6045元/50g;   展开

应用
Tetramethyldisilazane is used as a gas chromatographic derivatizing reagent. Further, it reacts with phenol to prepare dimethylphenoxysilane. In addition, it is used in electronic, polymer and pharmaceutical industries.

备注
Moisture sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00025626

EINECS
240-072-2

分子式
C4H15NSi2

分子量
133.34

沸点
99-100°

闪点
-3°(26°F)

密度
0.768

折射率
1.4055

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Miscible with common organic solvents.

Beilstein
741869

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H314-H318
Highly flammable liquid and vapour.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P280-P303+P361+P353-P305+P351+P338-P310
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
3

包装组
II

危险类别
11-34
Highly flammable.Causes burns.

安全等级
9-16-20-23-26-33-36/37/39-45-60
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

139246Sigma-Aldrich1,1,3,3-Tetramethyldisilazane97%586.82元/10 G;   展开

基本信息

线性分子式[(CH3)2SiH]2NH
分子量133.34
Beilstein741869
EC 号240-072-2
MDL编号MFCD00025626
PubChem化学物质编号24848399
NACRESNA.22

产品性质

质量水平100
测定97%
形式liquid
折射率n20/D 1.404 (lit.)
mp99-100 ℃
密度0.752 g/mL at 25 ℃ (lit.)
SMILES string[H][Si](C)(C)N[Si]([H])(C)C
InChI1S/C4H15NSi2/c1-6(2)5-7(3)4/h5-7H,1-4H3
InChI keyNQCZAYQXPJEPDS-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Danger
危险声明H225 - H315 - H319 - H335
预防措施声明P210 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)26.6 °F - closed cup
闪点(C)-3 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
928301Amethyst1,1,3,3-Tetramethyldisilazane97%, 试剂级356元/5ML;   671元/25ML;   展开

基本信息

分子式C4H15NSi2
分子量133.34
沸点99-100
闪点-3
密度0.752
折光率(n20D)1.404 - 1.406
MDL编码MFCD00025626
Beilstein741869
EINECS 编号240-072-2

安全信息

图形或危害标志
提示语Danger
危险说明H225
H315
H319
H335
防范说明P210
P261
P305+P351+P338
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK3
TSCA
S16100Fluorochem1,1,3,3-Tetramethyldisilazane95%1188元/25g;   3872元/100g;   展开

基本信息

CAS Number15933-59-2
MDL NumberMFCD00025626
Boiling Point99-100℃
Density0.766

安全信息

图形或危害标志
危险性说明 H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
防范说明 P210: Keep away from – No smoking.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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