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CAS: 1571-33-1
分子式: C6H7O3P
分子量: 158.09
熔点: 158-165℃
中文名称: 
苯基膦酸
英文名称: 
Phosphonic acid,phenyl-
Phenyl-phosphonic acid
Dihydrogen phenylphosphonate
Benzolphosphonsαure
Phenylphosphonsαure
phenyl-Phosphonic acid
benzenephosphonic acid
phenylphosphonic acid
phenyl-phosphonic aci
性质描述: 无色叶状结晶。熔点165℃,相对密度(20/4℃)1.475。易溶于水,溶于醇、醚和丙酮,不溶于苯及四氯化碳。
生产方法: 由苯膦酰二氯水解得到。
用途: 苯膦酸类化合物大量用于农药生产,新开发的用途是作为防污涂料的中间体,用于制造阴燃剂、催化剂等。
推荐供应商
货号品牌产品名称规格包装、参考价格
P830253MACKLIN苯膦酸98%28元/5g;   30元/25g;   70元/100g;   336元/500g;   1669元/2.5kg;   咨询
储存:室温,密封
状态:白色至类白色粉末或晶体或结晶粉末
P0204TCIPhenylphosphonic Acid>98.0%(T)165元/25G;   430元/100G;   1310元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C6H7O3P = 158.09
外观与形状(20℃)固体
Reaxys-RN2245168
PubChem物质ID87574450
SDBS (AIST Spectral DB)10133
MDL编号MFCD00002136

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Neutralization titration)min. 98.0 %
Melting point162.0 to 166.0 ℃
Solubility in Waterfaint turbidity
Solubility in Methanolfaint turbidity

物性(参考值)

熔点163 ℃
水溶性完全溶解
溶解性(可溶于)丙酮,氯仿,醇

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。

相关法规

RTECS#TA0350000
928555J&KPhenylphosphonic Acid98%218元/100G;   咨询

基本信息

分子式C6H7O3P
分子量158.09
熔点162-164
MDL编码MFCD00002136
Beilstein2245168
EINECS 编号216-388-1

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级III
WGK3
RTECSTA0350000
93-1537StremPhenylphosphonic Acid98%600元/50g;   2715元/250g;   9345元/1kg;   咨询
B22939Alfa AesarPhenylphosphonic Acid98%646元/100g;   3508元/500g;   咨询

应用
Phenylphosphonic acid additive used with Noyori's catalyst for oxidation of sulfides to sulfones. Used as additive of unsaturated polyester PU resin. It also can be added into nylon to improve its polymerization degree. It can be used as extreme pressure agent of lube; used as catalyst of carboxylic acid & alcohol reaction; it can be used as fire retarding treatment of fiber used asganic materials.

备注
Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

基本信息

MDL
MFCD00002136

EINECS
216-388-1

分子式
C6H7O3P

分子量
158.09

熔点
160-162°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water.

Beilstein
2245168

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
TA0350000

TSCA
是

C13079Alfa AesarPhenylphosphonic Acid98%1103元/100g;   2883元/500g;   14141元/2.5kg;   咨询

基本信息

Ref#
13079

MDL
2136

分子式
C6 H7 O3 P

分子量
158.09

安全信息

危险等级
8

包装组
III

P29006Sigma-AldrichPhenylphosphonic Acid98%475.96元/5 G;   774.75元/100 G;   2003.84元/500 G;   咨询

产品说明

应用

苯基膦酸的自组装单分子膜 (SAMs) 可用于制备有机半导体与透明导电氧化物之间的界面。酸可用于使二氧化钛颗粒功能化。与 Noyor® 催化剂配合使用,用于硫化物绿色氧化为砜。
与 Noyori 催化剂配合使用,用于将硫化物氧化为砜类的添加剂。

Noyori 氧化(二水合钨酸钠、过氧化氢、甲基三正辛基硫酸氢铵、磷酸)

包装

5, 100, 500 g in glass bottle

基本信息

线性分子式C6H5P(O)(OH)2
分子量158.09
Beilstein2245168
EC 号216-388-1
MDL编号MFCD00002136
PubChem化学物质编号24898371
NACRESNA.23

产品性质

质量水平200
测定98%
mp162-164 ℃ (lit.)
SMILES stringOP(O)(=O)c1ccccc1
InChI1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)
InChI keyQLZHNIAADXEJJP-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314
预防措施声明P260 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
099053FluorochemPhenylphosphonic Acid95%264元/25g;   550元/100g;   2376元/500g;   咨询

基本信息

CAS Number1571-33-1
MDL NumberMFCD00002136
Melting Point162-164℃
Density1.412

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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