CAS 15635-87-7; 三(乙酰丙酮根)合铱(III); iridium(iii) 2,4-pentanedionate

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I836217

MACKLIN

三(乙酰丙酮)合铱(III)

97%

205元/100mg; 470元/250mg; 1879元/1g; 9282元/5g;

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储存：室温,密封,干燥
状态：浅黄色到棕色粉末到晶体

I767451

MACKLIN

三(乙酰丙酮)合铱(III)

99.95% metals basis

799元/100mg;

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储存：室温, 密封, 干燥

T2557

TCI

Tris(2,4-pentanedionato)iridium(III)

2180元/1G;

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基本信息

分子式/分子量	C₁₅H₂₁IrO₆ = 489.54
外观与形状(20℃)	固体
Reaxys-RN	4148992
PubChem物质ID	87560700
MDL编号	MFCD00015353

技术规格

Appearance	Light yellow to Brown powder to crystal
Elemental analysis(Carbon)	35.0 to 38.6 %
iridium	38.0 to 41.0 %

物性(参考值)

熔点

271 ℃

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

194202

J&K

Iridium(III) 2,4-pentanedionate

97%

2693元/1G; 10431元/5G;

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基本信息

分子式	C₁₅H₂₁IrO₆
分子量	489.55
熔点	269-271
MDL编码	MFCD00015353
Beilstein	4148992
EINECS 编号	239-711-8

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H312 H315 H319 H332 H335 H351
防范说明	P261 P280 P305+P351+P338
WGK	3
TSCA	否

77-1500

Strem

Iridium(III) Acetylacetonate

98%

915元/250mg; 3180元/1g; 11880元/5g; 50415元/25g;

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Technical Notes

1.Precursor for preparation heterogeneous catalyst on different supports for various catalytic applications: organic reactions(1-3]; water oxidation4; co preferential oxidation]; oxygen evolutiono] reactions;

2.CVD/AL D precursor for preparation of Ir and Ir2C 3 films on different substrates7-9)

3. Starting material for synthesis of phosphorescent iridium complexes bearing arylpyridine ligandsl10]

References:

1.Appl. Catal, A 2003, 251, 131

2.Catal. Today., 2008, 133-135, 71 1

3.Green Chem., 2011, 13, 326

4.ACS Catal. 2012, 2, 2161

5.Chem. Mater., 2014, 26, 1654

6.Angew. Chem. Int. Ed. 2014, 53, 14016

7.Chem. Vap. Deposition 2006, 12, 419

8.Appl. Surf. Sci. 2007. 253, 4103

9. Catal. L ett.2007, 114, 135

10. Inorg. Chem., 2017. 6, 7533.

010514

Alfa Aesar

Iridium(III) 2,4-pentanedionate

Ir 37.5% min

0元/0.25g; 0元/1g; 0元/5g;

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应用
It is used as a photoreducing agent, a precursor for preparing Ir-C thin film and a catalyst for hydrogenation of sulfur containing compounds. Used in various catalysis reactions in organic synthesis, including carbon nanostructures.

备注
Stable in air.

基本信息

MDL
MFCD00015353

EINECS
239-711-8

分子式
C₁₅H₂₁IrO₆

分子量
489.53

熔点
269-271°

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Insoluble in water; soluble in chloroform and benzene; slightly soluble in ethanol and methanol.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

333352

Sigma-Aldrich

Iridium(III) Acetylacetonate

97%

3198.69元/500 MG; 12314.9元/2.5 G;

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基本信息

线性分子式	[CH₃COCH=C(O-)CH₃]₃Ir
分子量	489.54
EC 号	239-711-8
MDL编号	MFCD00015353
PubChem化学物质编号	24860124
NACRES	NA.23

产品性质

质量水平	100
测定	97%
形式	solid
reaction suitability	core: iridium reagent type: catalyst
mp	269-271 ℃ (lit.)
SMILES string	CC(=O)\C=C(\C)O[Ir](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
InChI	1S/3C5H8O2.Ir/c31-4(6)3-5(2)7;/h33,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InChI key	HLYTZTFNIRBLNA-LNTINUHCSA-K

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315 - H319 - H335 - H351
预防措施声明	P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
危险分类	Acute Tox. 4 Oral - Carc. 2 - Dermal - Inhalation - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves