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CAS: 1560-54-9
分子式: C21H20BrP
分子量: 383.27
熔点: 222-225℃
中文名称: 
烯丙基三苯基溴化膦
英文名称: 
allyltriphenyl-phosphoniu bromide
allyltriphenylphosphonium bromide
allyltriphenylphosphonium
allyltriphenylphosphoniumbromide
推荐供应商
货号品牌产品名称规格包装、参考价格
A821410MACKLIN烯丙基三苯基溴化膦99%29元/5g;   65元/25g;   230元/100g;   1002元/500g;   咨询
储存:室温
状态:白色结晶粉末
A769060MACKLIN烯丙基三苯基溴化膦92%55元/25g;   179元/100g;   咨询
储存:室温
A1007TCIAllyltriphenylphosphonium Bromide>98.0%(T)(HPLC)395元/25G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C21H20BrP = 383.27
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3579053
PubChem物质ID87562500
SDBS (AIST Spectral DB)18174
MDL编号MFCD00011808

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

熔点225 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#TA1843000
466687J&KAllyltriphenylphosphonium Bromide99%356元/50G;   1348元/250G;   咨询

基本信息

分子式C21H20BrP
分子量383.27
熔点222-225
MDL编码MFCD00011808

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
93-1501StremAllyltriphenylphosphonium Bromide99%430元/25g;   1292元/100g;   咨询
A14490Alfa AesarAllyltriphenylphosphonium Bromide99%784元/50g;   2981元/250g;   咨询

基本信息

MDL
MFCD00011808

EINECS
216-332-6

分子式
C21H20BrP

分子量
383.27

熔点
222-225°

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline powder

Beilstein
3579053

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
TA1843000

TSCA
否

C10304Alfa AesarAllyltriphenylphosphonium Bromide99%405元/25g;   925元/100g;   咨询

基本信息

Ref#
10304

MDL
11808

分子式
C21 H20 Br P

分子量
383.26

S280178ALLYL-TRIPHENYL-PHOSPHONIUM, BROMIDEAldrichCPR160.9元/25MG;   咨询

产品说明

其他说明

Please note that sigma-aldrich provides this product to early discovery researchers as part of a collection of rare and unique chemicals. sigma-aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH'S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT AS-IS AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

基本信息

线性分子式C21H20BrP
分子量383.271
MDL编号MFCD07189480
A36603Sigma-AldrichAllyltriphenylphosphonium Bromide99%838.55元/100 G;   咨询

产品说明

应用

Reactant for:

  • Preparation of a diol and carbamate chemistry library for common functional groups
  • Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
  • Alkene addition of frustrated Lewis pairs
  • Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
  • Wittig olefination of aldehydes for preparation of conjugated dienes
  • Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes

包装

100 g in poly bottle

基本信息

线性分子式H2C=CHCH2P(C6H5)3Br
分子量383.26
EC 号216-332-6
MDL编号MFCD00011808
PubChem化学物质编号24890798
NACRESNA.22

产品性质

测定99%
reaction suitabilityreaction type: C-C Bond Formation
mp222-225 ℃ (lit.)
SMILES string[Br-].C=CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
InChI keyFWYKRJUVEOBFGH-UHFFFAOYSA-M

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
222159FluorochemAllyltriphenylphosphonium Bromide95%220元/1g;   330元/25g;   968元/100g;   咨询

基本信息

CAS Number1560-54-9
MDL NumberMFCD00011808

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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