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CAS: 1519-39-7
分子式: C8H10OS
分子量: 154.23
沸点: 74℃
熔点: 74-76℃
英文名称: 
r(+)-methyl p-tolyl sulfoxide
1-Methanesulfinyl-4-methyl-benzene
(R)-methyl 4-methylphenyl sulfoxide
(R)-(+)-Methylp-tolyl sulfoxide
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基本信息

分子量
154.23

343609Sigma-Aldrich(R)-(+)-Methyl p-tolyl sulfoxide99%2164.29元/1 G;   展开

产品说明

一般描述

(R)-(+)-Methyl p-tolyl sulfoxide may be used to prepare (R)-(+)-methyl 3,5-dimethoxy-6-[8-oxo-9-(p-tolylsulfinyl) nonyl] benzoate, an intermediate for (R)-lasiodiplodin synthesis. Its anions undergo addition reaction with nitrones to form optically active a-substituted N-hydroxylamines. (R)-(+)-Methyl p-tolyl sulfoxide also reacts with O-mesitylsulfonylhydroxylamine (MSH) to form (-)-(R)-S-methyl-S-p-tolylsulfoximine.

包装

1 g in glass bottle

基本信息

线性分子式CH3C6H4S(O)CH3
分子量154.23
Beilstein2040677
MDL编号MFCD00151502
PubChem化学物质编号24861180
NACRESNA.22

产品性质

测定99%
旋光性[α]20/D +145°, c = 2 in acetone
光学纯度ee: 99% (HPLC)
mp73-75 ℃ (lit.)
SMILES stringCc1ccc(cc1)S(C)=O
InChI1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3/t10-/m1/s1
InChI keyFEVALTJSQBFLEU-SNVBAGLBSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
305888Fluorochem(R)-Methyl p-tolyl sulfoxide95%2156元/250mg;   5390元/1g;   展开

基本信息

CAS Number1519-39-7
MDL NumberMFCD00151502

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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