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CAS: 1517-82-4
分子式: C17H26O2S
分子量: 294.45
熔点: 99-104℃
英文名称: 
(1R,2S,5R)-(-)-Menthyl(S)-p-toluenesulfinate
(-)-(1R)-Menthyl(S)-p-toluenesulfinate
(-)-(1R)-menthyl (S)-toluene-4-sulfinate
推荐供应商
货号品牌产品名称规格包装、参考价格
R814217MACKLIN(1R,2S,5R)-(-)-薄荷基(|S|)-对甲苯亚磺酸酯98%31元/1g;   108元/5g;   479元/25g;   咨询
储存:-20°C
状态:白色到浅黄色结晶粉末
折射率:-199 ° (C=1.5, Acetone)
M1044TCI(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate>98.0%(HPLC)980元/5G;   2990元/25G;   咨询

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C17H26O2S = 294.45
外观与形状(20℃)固体
储存温度<0℃
应避免的情况加热
Reaxys-RN4295405
PubChem物质ID87573015
SDBS (AIST Spectral DB)19131
MDL编号MFCD00010192

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(HPLC)min. 98.0 area%
Melting point101.0 to 107.0 ℃
Specific rotation [a]20/D-195.0 to -205.0 deg(C=2, Acetone)

物性(参考值)

熔点105 ℃
比旋光度 [α]D-200° (C=2,Acetone)
137096J&K(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate97%463元/1G;   2010元/5G;   咨询

基本信息

分子式C17H26O2S
分子量294.45
熔点102-104
比旋光度([α]20D)-204.0° to 190.0° (C=2, Acetone)
MDL编码MFCD00010192
Beilstein3207468
存储条件Freezer -20℃

安全信息

防范说明P262
WGK3
C42811Alfa Aesar(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate98%713元/1g;   4160元/10g;   咨询

基本信息

Ref#
42811

MDL
10192

分子式
C17 H26 O2 S

分子量
294.46

278750Sigma-Aldrich(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate98%1658.65元/10 G;   咨询

产品说明

一般描述

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

应用

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:

  • metal ketimines to form enantiopure sulfinimines
  • p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine

包装

10 g in glass bottle

基本信息

经验(实验)分子式C17H26O2S
分子量294.45
Beilstein3207468
PubChem化学物质编号24856828
NACRESNA.22

产品性质

质量水平200
测定98%
旋光性[α]20/D −195°, c = 2 in acetone
mp102-104 ℃ (lit.)
储存温度−20℃
SMILES stringC[C@@H]1CC[C@@H](C(C)C)[C@@H](C1)OS(=O)c2ccc(C)cc2
InChI1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m1/s1
InChI keyNQICGNSARVCSGJ-ASKNOMKYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
219814Fluorochem(1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate95%220元/250mg;   506元/1g;   1298元/5g;   4664元/25g;   咨询

基本信息

CAS Number1517-82-4
MDL NumberMFCD23701383
Melting Point102 - 104 ℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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