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CAS: 15159-40-7
分子式: C5H8ClNO2
分子量: 149.57
英文名称: 
4-Morpholinylcarbonyl Chloride
4-Chlorocarbonylmorpholine
Morpholinocarbonyl Chloride
4-morpholinecarbonyl chloride
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货号品牌产品名称规格包装、参考价格详情
M831544MACKLIN4-吗啉碳酰氯97%60元/5g;   232元/25g;   801元/100g;   展开
储存:室温,密封
状态:无色到淡黄色液体
M0935TCI4-Morpholinylcarbonyl Chloride>97.0%(GC)(T)555元/25G;   1485元/100G;   展开

基本信息

纯度/分析方法>97.0%(GC)(T)
分子式/分子量C5H8ClNO2 = 149.57
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN116257
PubChem物质ID87572917
MDL编号MFCD00037053

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 97.0 %
Purity(Argentometric Titration)min. 97.0 %

物性(参考值)

沸点138 ℃/33 mmHg
比重1.31
折射率1.50

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H351 : 怀疑致癌。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P234 : 只能在原容器中存放。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 III
监管条件代码(*)
451000J&K4-Morpholinylcarbonyl Chloride98%1136元/100G;   展开

基本信息

分子式C5H8ClNO2
分子量149.58
沸点137-138
闪点113
密度1.282
折光率(n20D)1.498
MDL编码MFCD00037053
Beilstein116257
EINECS 编号239-213-0

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H351
防范说明P281
P305+P351+P338
UN号码3265
危险分类8
包装等级II
WGK3
348295Sigma-Aldrich4-Morpholinecarbonyl chloride98%698.78元/25 G;   展开

产品说明

一般描述

4-Morpholinecarbonyl chloride is a photographic intermediate. Rates of solvolysis of 4-morpholinecarbonyl chloride with N-alkyl group in aqueous binary solvents of acetone, ethanol, methanol, methanol-d, 2,2,2-trifluoroethanol, pure water and D2O has been determined. Preparation of 4-morpholinecarbonyl chloride has been reported.

应用

4-Morpholinecarbonyl chloride may be used in the preparation of a versatile fluorogenic label for biomolecular imaging. It may be used in the synthesis of:

  • morpholine-4-carboxylic acid [4-(2,4-dimethylphenyl)thiazol-2-yl]amide
  • morpholine-4-carboxylic acid [4-(2,4,6-trimethylphenyl)thiazol-2-yl]amide
  • 2-isopropyl-6-methylpyrimidin-4-yl morpholine-4-carboxylate

包装

25, 100 g in glass bottle

基本信息

经验(实验)分子式C5H8ClNO2
分子量149.58
Beilstein116257
EC 号239-213-0
MDL编号MFCD00037053
PubChem化学物质编号24861562
NACRESNA.22

产品性质

质量水平200
测定98%
折射率n20/D 1.498 (lit.)
bp137-138 ℃/33 mmHg (lit.)
密度1.282 g/mL at 25 ℃ (lit.)
SMILES stringClC(=O)N1CCOCC1
InChI1S/C5H8ClNO2/c6-5(8)7-1-3-9-4-2-7/h1-4H2
InChI keyXMWFMEYDRNJSOO-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H315 - H319 - H351
预防措施声明P201 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
补充剂危害EUH014
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
935329Amethyst4-Morpholinylcarbonyl Chloride98%, 用于合成1022元/100G;   展开

基本信息

分子式C5H8ClNO2
分子量149.58
闪点113
MDL编码MFCD00037053
Beilstein116257
EINECS 编号239-213-0

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H351
防范说明P281
P305+P351+P338
UN号码3265
危险分类8
包装等级II
WGK3
448632FluorochemMorpholine-4-carbonyl chloride95%220元/1g;   528元/5g;   902元/10g;   展开

基本信息

CAS Number15159-40-7
MDL NumberMFCD00037053
Density1.31

安全信息

图形或危害标志
危险性说明 EUH014: Reacts violently with water.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H351: Suspected of causing cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe
P264: Wash hands thoroughly after handling.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local and national regulations.
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