[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 14937-45-2
关键词:       仅模糊查询
CAS: 14937-45-2
分子式: C28H60BrP
分子量: 507.67
熔点: 57-60℃
中文名称: 
溴化十六烷基三丁基磷
十六烷基三丁基溴化磷
十六烷基三丁基溴化鏻
英文名称: 
tributylhexadecyl-phosphoniu bromide
hexadecyltri-n-butylphosphonium bromide
hexadecyltributyl ammonium bromide
性质描述: 白色结晶。熔点56-58℃。
生产方法: 将等摩尔1-溴代正十六烷和三丁基膦在65℃反应3d,所得固体产物在已烷中重结晶,真空干燥,得溴化十六烷基三丁基膦,收率68%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T838602MACKLIN十六烷基三丁基溴化鏻98%77元/5g;   335元/25g;   1335元/100g;   展开
储存:室温
状态:白色到灰白色粉末或晶体或块状
T708905MACKLIN十六烷基三丁基溴化鏻95%67元/5g;   334元/25g;   1332元/100g;   展开
储存:室温
H1047TCITributylhexadecylphosphonium Bromide>98.0%(T)850元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C28H60BrP = 507.67
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN4167404
PubChem物质ID87571394
MDL编号MFCD00011775

技术规格

AppearanceWhite powder to lump
Purity(Nonaqueous Titration)min. 98.0 %
Melting point59.0 to 63.0 ℃

物性(参考值)

熔点61 ℃
水溶性完全溶解

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
93-1581StremHexadecyltri-n-butylphosphonium bromide98+%1020元/10g;   4020元/50g;   展开
L01335Alfa Aesar(n-Hexadecyl)tri-n-butylphosphonium bromide98+%498元/5g;   1646元/25g;   4756元/100g;   展开

应用
(n-Hexadecyl)tri-n-butylphosphonium bromide is used as Phase-transfer-catalyst. It is a eco friendly highly effective water treatment agent with low foaming and toxic-free.

备注
Hygroscopic. Protect from carbondioxide. Store away from moisture.

基本信息

MDL
MFCD00011775

EINECS
239-014-9

分子式
C28H60BrP

分子量
507.67

熔点
56-62°

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Powder

溶解性
Soluble in methanol.

Beilstein
4167404

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

276200Sigma-AldrichTributylhexadecylphosphonium Bromide97%333.26元/5 G;   925.81元/25 G;   2392.37元/100 G;   展开

基本信息

线性分子式CH3(CH2)15P+[(CH2)3CH3]3Br-
分子量507.65
Beilstein4167404
EC 号239-014-9
MDL编号MFCD00011775
PubChem化学物质编号24856693

产品性质

质量水平100
测定97%
mp56-58 ℃ (lit.)
SMILES string[Br-].CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC
InChI1S/C28H60P.BrH/c1-5-9-13-14-15-16-17-18-19-20-21-22-23-24-28-29(25-10-6-2,26-11-7-3)27-12-8-4;/h5-28H2,1-4H3;1H/q+1;/p-1
InChI keyRYVBINGWVJJDPU-UHFFFAOYSA-M

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
069284FluorochemTributylhexadecylphosphonium Bromide98%286元/5g;   506元/10g;   880元/25g;   2904元/100g;   展开

基本信息

CAS Number14937-45-2
MDL NumberMFCD00011775

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9