应用
5-Hexynenitrile is used in the preparation of annelated symmetric and asymmetric 3,3'-disubstituted 2,2'-bipyridines by cobalt(I)-catalyzed [2+2+2] cycloadditions with 1,3-diynes. Further, it reacts with 3-bromo-pyridine to prepare 6-(3-pyridinyl)-5-hexynenitrile.

备注
Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00001978

分子式
HC≡CCH₂CH₂CH₂CN

分子量
93.13

沸点
115-117°

闪点
42°(107°F)

密度
0.889

折射率
1.4410

灵敏度
Keep Cold.

形态
Liquid

溶解性
Miscible with water.

Beilstein
1735926

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H302-H312-H332
Flammable liquid and vapour.Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.

Precautionary Statements
P210-P261-P280-P303+P361+P353-P304+P340-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-20/21/22
Flammable.Harmful by inhalation, in contact with skin and if swallowed.

安全等级
9-23-36/37-60
Keep container in a well-ventilated place.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

基本信息

Ref#
30737

MDL
1978

分子式
C6 H7 N

分子量
93.13

闪点
42

密度
0.88

安全信息

危险等级
3

包装组
III

产品说明

应用

5-Hexynenitrile was used in the synthesis of annelated symmetric and asymmetric 3,3′-disubstituted 2,2′-bipyridines by cobalt(I)-catalyzed [2+2+2] cycloadditions with 1,3-diynes.

包装

1, 5 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H226 - H302 + H312 + H332 - H315 - H319 - H335
预防措施声明	P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	107.6 °F - closed cup
闪点(C)	42 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P370 + P378: In case of fire: Use CO2, dry powder or foam for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.