| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| A960454 | MACKLIN | 二羰基乙酰丙酮铑 | 98% | 743元/250mg; 2210元/1g; | 展开 |
储存：室温 状态：绿色或深绿色或棕色粉末或晶体或针状 |
| A801414 | MACKLIN | 二羰基乙酰丙酮铑 | 99% | 1299元/250mg; 2996元/1g; 12999元/5g; | 展开 |
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| 45-0700 | Strem | Dicarbonylacetylacetonato rhodium(I) | 99% | 2642元/250mg; 7924元/1g; 30861元/5g; | 展开 |
Technical Notes: 1.Precatalyst for hydroformylation of olefins. 2.Precatalyst for silylformylation of olefins. 3.Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids. 4. Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones. References: 1.Synthesis, 2001, 1. 2.Org. L ett., 2009, 1 1, 2659. 3.J. Am. Chem. Soc., 1997, 1 19, 12416. 4.J. Am. Chem. Soc., 2009, 131, 141 88. 5. Organometallics, 1997, 16, 4229. 6.Org. L ett., 2009, 1 1, 971. |
| 039295 | Alfa Aesar | Dicarbonyl(2,4-pentanedionato)rhodium(I) | 97% | 0元/250mg; 0元/1g; 0元/5g; | 展开 |
应用
(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction. 备注
Store in a cool, dry place in a tightly sealed container. Air and moisture stable. 基本信息 MDL
MFCD00009884 EINECS
238-947-9 分子式
C7H7RhO4 分子量
258.04 熔点
144-147° subl. 灵敏度
Ambient temperatures. 形态
Crystalline 溶解性
Soluble in acetone GHS危害和防范说明 GHS符号
  Hazard Statements
H228-H301-H319-H317-H412
Flammable solid.Toxic if swallowed.Causes serious eye irritation.May cause an allergic skin reaction.Harmful to aquatic life with long lasting effects. Precautionary Statements
P210-P261-P301+P310a-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Avoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
6.1 包装组
III 危险类别
11-25-36-43-53
Highly flammable.Toxic if swallowed.Irritating to eyes.May cause sensitization by skin contact.May cause long-term adverse effects in the aquatic environment. 安全等级
20-24-26-37-45-61
When using do not eat or drink.Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets. 欧盟危险品标志
 TSCA
否 |
| C36395 | Alfa Aesar | Dicarbonylacetylacetonato rhodium(I) | | 7115元/500mg; 31811元/2.5g; | 展开 |
基本信息 Ref#
36395 MDL
9884 分子式
C7 H7 O4 Rh 分子量
258.04 |
| 288101 | Sigma-Aldrich | (Acetylacetonato)dicarbonylrhodium(I) | 98% | 6036.34元/1 G; | 展开 |
产品说明 包装 1 g in glass bottle 应用 在分子工程中用于所关注的氟溶氢甲酰化催化剂的原位形成。 基本信息 | 线性分子式 | Rh(CO)2(C5H7O2) | | 分子量 | 258.03 | | EC 号 | 238-947-9 | | MDL编号 | MFCD00009884 | | PubChem化学物质编号 | 24857317 |
产品性质 | 质量水平 | 100 | | 测定 | 98% | | 形式 | solid | | reaction suitability | reagent type: catalyst | | mp | 154-156 ℃ (lit.) | | SMILES string | [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh] | | InChI | 1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;; | | InChI key | BZCAWKOPWNIDOC-FGSKAQBVSA-M |
安全信息 | 象形图 |  | | 警示用语： | Warning | | 危险声明 | H228 - H317 - H319 | | 预防措施声明 | P210 - P240 - P241 - P280 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Flam. Sol. 2 - Skin Sens. 1 | | 补充剂危害 | EUH044 | | 储存分类代码 | 4.1B - Flammable solid hazardous materials | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 683183 | Sigma-Aldrich | CARAC | Umicore, 98% | 3387.1元/500 MG; 11114.3元/2 G; | 展开 |
产品说明 应用 Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds 包装 2 g in glass bottle
500 mg in glass bottle 法律信息 Product of Umicore
Additional information available at www.pmc.umicore.com 基本信息 | 线性分子式 | Rh(CO)2(C5H7O2) | | 分子量 | 258.03 | | EC 号 | 238-947-9 | | MDL编号 | MFCD00009884 | | PubChem化学物质编号 | 329760803 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 98% | | 形式 | solid | | reaction suitability | core: rhodium
reagent type: catalyst | | mp | 154-156 ℃ (lit.) | | SMILES string | [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh] | | InChI | 1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;; | | InChI key | BZCAWKOPWNIDOC-FGSKAQBVSA-M |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H228 - H317 - H319 | | 预防措施声明 | P210 - P240 - P241 - P280 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Flam. Sol. 2 - Skin Sens. 1 | | 补充剂危害 | EUH044 | | 储存分类代码 | 4.1B - Flammable solid hazardous materials | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 379058 | Fluorochem | Dicarbonylacetylacetonato rhodium(I) | 95% | 1430元/250mg; 4840元/1g; 23540元/5g; | 展开 |
基本信息 | CAS Number | 14874-82-9 | | MDL Number | MFCD00009884 | | Melting Point | 155℃ | | Density | 1.96 |
安全信息 | 图形或危害标志 |  | | 危险性说明 | EUH044: Risk of explosion if heated under confinement.
H228: Flammable solid.
H301: Toxic if swallowed.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
H411: Toxic to aquatic life with long lasting effects.
H317: May cause an allergic skin reaction
| | 防范说明 | P210: Keep away from – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2, foam or extinguishing powder for extinction.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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