CAS 14871-41-1; 羰基氯双三苯基磷基铱(I); Bis(triphenylphosphine)iridium(I)carbonyl chloride

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C823806

MACKLIN

羰基氯化双(三苯基膦)铱(I)

95%

1043元/250mg; 3073元/1g; 14000元/5g;

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储存：室温
状态：柠檬黄色晶体

C2252

TCI

Carbonylchlorobis(triphenylphosphine)iridium(I)

>95.0%(T)

725元/200MG; 2610元/1G;

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基本信息

纯度/分析方法	>95.0%(T)
分子式/分子量	C₃₇H₃₀ClIrOP₂ = 780.26
外观与形状(20℃)	固体
包装和容器	1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN	14517301
PubChem物质ID	253660140
MDL编号	MFCD00009590

技术规格

Appearance	Light yellow to Yellow to Orange powder to crystal
Purity(Argentometric Titration)	min. 95.0 %

物性(参考值)

熔点	225 ℃(dec.)
最大吸收波长	385 nm

安全信息

图形或危害标志
信号词	危险
危险性说明	H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P311 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P405 : 存放处须加锁。

运输信息

UN编号	UN2811
类别	6.1
包装类别	III
监管条件代码(*)

77-0300

Strem

Chlorocarbonylbis(triphenylphosphine)iridium(I)

99%

765元/250mg; 2145元/1g; 8505元/5g;

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Technical Notes

1.Catalyst for the intramolecular carbonylative 2+2+ 1 cycloaddition of allenynes .

2.Catalyst for the selective hydrogenation of myrcene.

3.Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes .

4.Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mildconditions.

5.Hydrogen atom transfer catalyst for radical cyclizations .

6.Complex for photocatalytic alkane dehydrogenation.

7.Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.

8.Catalyst for chemoselective reductive alkynylation of tertiary amides.

039413

Alfa Aesar

Carbonylchlorobis(triphenylphosphine)iridium(I)

0元/0.25g; 0元/1g; 0元/5g;

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应用
Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

备注
Store away from oxidizing agents in a cool, dry place in a well-sealed container.

基本信息

MDL
MFCD00009590

EINECS
238-941-6

分子式
IrCl(CO)[P(C₆H₅)₃]₂

分子量
780.27

熔点
215° dec.

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.

Precautionary Statements
P261-P280h-P304+P340-P311a-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/clothing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22
Harmful by inhalation, in contact with skin and if swallowed.

安全等级
4-9-20-36/37/39-45-60
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是