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CAS: 148461-14-7
分子式: C24H24NOP
分子量: 373.43
熔点: 77-80℃
英文名称: 
diphenylphosphinophenylmethylethyldihydrooxazole
推荐供应商
货号品牌产品名称规格包装、参考价格
S818245MACKLIN(S)-2-(2-(二苯基膦基)苯基)-4-异丙基-4,5-二氢恶唑98%59元/100mg;   249元/500mg;   428元/1g;   咨询
储存:室温, 惰性气体
状态:白色至黄色粉末或晶体
177081J&K(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline97%957元/50MG;   4082元/250MG;   咨询

基本信息

分子式C24H24NOP
分子量373.43
熔点87-90
比旋光度([α]20D)-51° to -45° (C=1, CHCl3)
MDL编码MFCD03414150
Beilstein5879302

安全信息

防范说明P262
WGK3
15-1822Strem(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole98%1290元/50mg;   4198元/250mg;   12622元/1g;   咨询

Technical Notes:

1. Chiral ligand used in the asymmetric reduction of highly substituted olefins

2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to

the fact that the catalytic system does not promote double bond isomerization.

2.Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole .

3.Decarboxylative allylic alkylation.

References:

1. Angew. Chem. Int. Ed., 1998, 37, 2897.

2. Angew. Chem. Int. ., 1996, 35, 200.

3. Acc. Chem. Res. 2000, 33, 336.

4. Eur. J. Org. Chem.. 2011, 31, 6288.

5. Org. Lett., 2014, 16, 118.

Y10262Alfa Aesar(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo460元/100mg;   852元/250mg;   2332元/1g;   咨询

基本信息

分子量
373.44

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