CAS 1483-72-3; 氯代二苯碘翁; Iodonium,diphenyl-,chloride

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D838082

MACKLIN

氯代二苯碘鎓

≥98 %

60元/1g; 241元/5g; 896元/25g;

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储存：室温，干燥
状态：白色到淡黄色固体

D2356

TCI

Diphenyliodonium Chloride

>98.0%(T)

695元/5G; 2250元/25G;

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基本信息

纯度/分析方法	>98.0%(T)
分子式/分子量	C₁₂H₁₀ClI = 316.57
外观与形状(20℃)	固体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,空气,加热
Reaxys-RN	3574977
PubChem物质ID	87568792
SDBS (AIST Spectral DB)	13148
MDL编号	MFCD00011909

技术规格

Appearance	White to Light yellow powder to crystal
Purity(HPLC)	min. 95.0 area%
Purity(Argentometric Titration)	min. 98.0 %
Solubility in Methanol	very faint turbidity

物性(参考值)

溶解性(可溶于)

甲醇

安全信息

图形或危害标志
信号词	危险
危险性说明	H301 : 吞咽会中毒。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P405 : 存放处须加锁。

相关法规

RTECS#

NN6651666

运输信息

UN编号	UN2811
类别	6.1
包装类别	III
监管条件代码(*)

403687

J&K

Diphenyliodonium Chloride

98%

154元/1G; 295元/5G;

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基本信息

分子式	C₁₂H₁₀ClI
分子量	316.57
熔点	233-235
MDL编码	MFCD00011909
Beilstein	3574977
EINECS 编号	216-049-8

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H315 H319 H335
防范说明	P261 P301+P310 P305+P351+P338
UN号码	2811
危险分类	6.1
包装等级	III
WGK	3
RTECS	NN6651666

A15149

Alfa Aesar

Diphenyliodonium Chloride

98+%

1584元/10g; 7648元/50g; 30316元/250g;

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应用
Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.

备注
Light sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00011909

EINECS
216-049-8

分子式
C₁₂H₁₀ClI

分子量
316.57

熔点
ca 230° dec.

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water and methanol.

Beilstein
3574977

Merck
14,7464

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25-36/37/38
Toxic if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
20-26-36/37-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
NN6651666

TSCA
是

C11733

Alfa Aesar

Diphenyliodonium Chloride

97%

8153元/10g; 39585元/50g;

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基本信息

Ref#
11733

MDL
11909

分子式
C12 H10 I . Cl

分子量
316.57

安全信息

危险等级
6.1

包装组
III

43088

Sigma-Aldrich

Diphenyliodonium Chloride

≥98.0% (AT)

731.14元/5 G; 2328.12元/25 G;

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产品说明

应用

用作以下过程的反应物：

铜催化嘌呤与二芳基碘的交叉偶联反应
炔芳基硒醚的合成
薗头偶联反应制备芳基炔烃
(芳亚甲基)吲哚的 C-H 官能团化合成
苯胺的芳基化
可见光光敏系统 - 荧光黄-二(di-Ph 錪鎓)的研究
分散光酸直接光解和敏化光解属性的研究

包装

5, 25 g in glass bottle

其他说明

用于亲电苯基化反应(如丙二酸酯和二硫代羧酸酯的反应)的试剂

基本信息

线性分子式	(C₆H₅)₂I⁺Cl^-
分子量	316.57
Beilstein	3574977
EC 号	216-049-8
MDL编号	MFCD00011909
PubChem化学物质编号	57650143
NACRES	NA.22

产品性质

质量水平	200
测定	≥98.0% (AT)
reaction suitability	reagent type: oxidant
mp	233-235 ℃ (subl.) (lit.)
SMILES string	[Cl-].[I+](c1ccccc1)c2ccccc2
InChI	1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
InChI key	RSJLWBUYLGJOBD-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Danger
危险声明	H301 - H315 - H319 - H335
预防措施声明	P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

911353

Amethyst

Diphenyliodonium Chloride

98%, 用于合成

115元/1G; 410元/5G; 1908元/25G;

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基本信息

分子式	C₁₂H₁₀ClI
分子量	316.57
熔点	233-235
MDL编码	MFCD00011909
Beilstein	3574977
EINECS 编号	216-049-8

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H315 H319 H335
防范说明	P261 P301+P310 P305+P351+P338
UN号码	2811
危险分类	6.1
包装等级	III
WGK	3
RTECS	NN6651666

540454

Fluorochem

Diphenyliodonium Chloride

97%

330元/1g; 1056元/5g; 1980元/10g; 4752元/25g;

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基本信息

CAS Number	1483-72-3
MDL Number	MFCD00011909

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.