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CAS: 14812-59-0
分子式: C6H12ClO2P
分子量: 182.58
沸点: 81.5-82 °C/13 mmHg(lit.)
英文名称: 
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
4,4,5,5-Tetramethyl-2-chloro-1,3,2-dioxaphospholane
2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxa- phosphol
推荐供应商
货号品牌产品名称规格包装、参考价格
C874783MACKLIN2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷95%190元/50mg;   579元/200mg;   1701元/1g;   6397元/5g;   24870元/25g;   咨询
储存:2-8℃, 干燥, 惰性气体保护
状态:澄清到浑浊无色液体

应用领域:

2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (TMDP) can be used:

• As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands.
• As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis.

447536Sigma-Aldrich2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane95%2147.25元/1 G;   7214.9元/5 G;   咨询

产品说明

应用

2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷(TMDP)可用于:

  • 作为试剂用于将醇类和杂原子亲核体类化合物通过亚磷酰化(phosphitylation)反应合成有用的糖基供体和配体。
  • 作为亚磷酰化试剂将木质素样品衍生化用于31P NMR分析。

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C6H12ClO2P
分子量182.59
MDL编号MFCD00274239
PubChem化学物质编号24868346
NACRESNA.22

产品性质

测定95%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率n20/D 1.471 (lit.)
bp81.5-82 ℃/13 mmHg (lit.)
密度1.149 g/mL at 25 ℃ (lit.)
官能团phosphine
SMILES stringCC1(C)OP(Cl)OC1(C)C
InChI1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3
InChI keyWGPCXYWWBFBNSS-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类Eye Dam. 1 - Skin Corr. 1B
补充剂危害EUH014
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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