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CAS: 147081-49-0
分子式: C9H18N2O2
分子量: 186.25
沸点: 243℃
熔点: 243-244 °C
中文名称: 
(R)-3-氨基-1-N-BOC-吡咯烷
(R)-1-BOC-3-氨基吡咯烷
(R)-1-叔丁氧羰基-3-氨基吡咯烷
英文名称: 
(R)-1-tert-Butoxycarbonyl-3-aminopyrrolidine
(R)-(+)-n-boc-3-aminopyrrolidine
(R)-1-Boc-3-Aminopyrrolidine
(R)-3-Amino-1-N-Boc-pyrrolidine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
R803063MACKLIN|R|-(+)-1-Boc-3-氨基吡咯烷 97%30元/1g;   96元/5g;   430元/25g;   1698元/100g;   展开
储存:室温
状态:无色到棕色液体
折射率:1.4720
R742598MACKLIN|R|-(+)-1-Boc-3-氨基吡咯烷Standard for GC, ≥99.9%(GC)300元/1g;   展开
储存:室温
状态:液体
R742599MACKLIN|R|-(+)-1-Boc-3-氨基吡咯烷99%42元/1g;   134元/5g;   651元/25g;   展开
储存:室温
状态:液体
B2920TCI(3R)-(+)-1-(tert-Butoxycarbonyl)-3-aminopyrrolidine>98.0%(GC)(T)180元/1G;   690元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H18N2O2 = 186.26
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN9846394
PubChem物质ID87559536
MDL编号MFCD03427030

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 98.0 %
Optical purity(GC)min. 97.0 ee%
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

沸点244 ℃
闪点91 ℃
比重1.03
比旋光度 [α]D4° (C=1,CHCl3)
折射率1.47

安全信息

图形或危害标志
信号词危险
危险性说明H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
401864J&K(R)-(+)-1-Boc-3-aminopyrrolidine97%, ee: 98%1794元/1G;   6692元/5G;   展开

基本信息

分子式C9H18N2O2
分子量186.25
沸点243-244
闪点91
密度1.098
折光率(n20D)1.4690 - 1.4730
比旋光度([α]20D)+2° to +4° (C=1, CHCl3)
MDL编码MFCD03419272
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H301
H318
防范说明P280
P301+P310
P305+P351+P338
UN号码2810
危险分类6.1
包装等级III
WGK3
TSCA
H28188Alfa Aesar(R)-(+)-1-Boc-3-aminopyrrolidine97%4244元/1g;   9639元/5g;   展开

基本信息

MDL
MFCD03419272

分子式
C9H18N2O2

分子量
186.25

沸点
243-244°

闪点
91°(196°F)

密度
1.098

折射率
1.4720

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

644064Sigma-Aldrich(R)-(+)-1-Boc-3-aminopyrrolidine97%1729.87元/5 G;   展开

产品说明

应用

(R)-(+)-1-Boc-3-aminopyrrolidine may be used to prepare:

  • Descarboxamide analog and Na-methylated analogs of 4-N-(Nω-nitro-L-argininyl)-trans-4-amino-L-proline amide.
  • Histamine 3 (H3) receptor antagonists containing pyrrolidin-3-yl-N-methylbenzamide moiety.

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C9H18N2O2
分子量186.25
MDL编号MFCD03419272
PubChem化学物质编号24883312
NACRESNA.22

产品性质

质量水平100
测定97%
折射率n20/D 1.472 (lit.)
bp243-244 ℃ (lit.)
密度1.098 g/mL at 25 ℃ (lit.)
SMILES stringCC(C)(C)OC(=O)N1CC[C@@H](N)C1
InChI1S/C9H18N2O2/c1-9(2,3)13-8(12)11-5-4-7(10)6-11/h7H,4-6,10H2,1-3H3/t7-/m1/s1
InChI keyCMIBWIAICVBURI-SSDOTTSWSA-N

安全信息

象形图GHS05GHS06
警示用语:Danger
危险声明H301 - H318
预防措施声明P280 - P301 + P310 + P330 - P305 + P351 + P338 + P310
危险分类Acute Tox. 3 Oral - Eye Dam. 1
补充剂危害EUH044
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)196.0 °F - closed cup
闪点(C)91.1 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
011315Fluorochem(R)-3-Amino-1-N-Boc-pyrrolidine98%220元/1g;   594元/5g;   990元/10g;   1540元/25g;   展开

基本信息

CAS Number147081-49-0
MDL NumberMFCD03419272
Boiling Point243-244℃
Melting Point243-244℃
Density1.098

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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