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CAS: 147081-44-5
分子式: C9H18N2O2
分子量: 186.25
沸点: 216-217 °C(lit.)
中文名称: 
(S)-1-BOC-3-氨基吡咯烷
(S)-1-叔丁氧羰基-3-氨基吡咯烷
英文名称: 
(S)-1-tert-Butoxycarbonyl-3-aminopyrrolidine
(S)-n-boc-3-aminopyrrolidine
(S)-1-Boc-3-Aminopyrrolidine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N803064MACKLIN|S|-(-)-1-Boc-3-氨基吡咯烷98%30元/1g;   109元/5g;   434元/25g;   1620元/100g;   展开
储存:室温
状态:无色到浅黄色液体
折射率:n20/D 1.4720(lit.)
B2921TCI(3S)-(-)-1-(tert-Butoxycarbonyl)-3-aminopyrrolidine>98.0%(GC)(T)195元/1G;   895元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H18N2O2 = 186.26
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN8312125
PubChem物质ID87559537
MDL编号MFCD03419271

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 98.0 %
Optical purity(GC)min. 98.0 ee%
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

沸点217 ℃
比重1.03
比旋光度 [α]D-3° (C=1,CHCl3)
折射率1.47

安全信息

图形或危害标志
信号词危险
危险性说明H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
136634J&K(S)-(-)-1-Boc-3-aminopyrrolidine98%180元/1G;   596元/5G;   展开

基本信息

分子式C9H18N2O2
分子量186.25
沸点216-217
闪点91
密度1.067
折光率(n20D)1.4720
比旋光度([α]20D)-5° to -2° (C=1, CHCl3)
MDL编码MFCD03419271
Beilstein8312125

安全信息

图形或危害标志
提示语Danger
危险说明H301
H318
防范说明P280
P301+P310
P305+P351+P338
UN号码2810
危险分类6.1
包装等级III
WGK2
TSCA
L19696Alfa Aesar(S)-(-)-1-Boc-3-aminopyrrolidine95%1659元/1g;   5671元/5g;   展开

应用
(S)-(-)-1-Boc-3-aminopyrrolidine is specifically used to protect amine in the solid phase synthesis of peptides. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals agrochemicals and dyestuff fields.

备注
Store under inert gas. It is sensitive to air. Store in a cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

基本信息

MDL
MFCD03419271

EINECS
627-302-0

分子式
C9H18N2O2

分子量
186.25

沸点
115°/4mm

密度
1.020

折射率
1.4715

灵敏度
Keep Cold. Air Sensitive. Store under Nitrogen.

形态
Liquid

Beilstein
8312125

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260-P280-P305+P351+P338-P309-P310
Do not breathe dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
6.1

包装组
III

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

634794Sigma-Aldrich(S)-(-)-1-Boc-3-aminopyrrolidine95%464.83元/1 G;   1368.72元/5 G;   展开

产品说明

应用

(S)-(-)-1-Boc-3-aminopyrrolidine may be used to prepare:

  • Descarboxamide analog of 4-N-(Nω-nitro-L-argininyl)-trans-4-amino-L-proline amide.
  • Histamine 3 (H3) receptor antagonists containing pyrrolidin-3-yl-N-methylbenzamide moiety.

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C9H18N2O2
分子量186.25
MDL编号MFCD03419271
PubChem化学物质编号24882650
NACRESNA.22

产品性质

质量水平100
测定95%
旋光性[α]20/D −2°, c = 1 in chloroform
折射率n20/D 1.4720 (lit.)
bp216-217 ℃ (lit.)
密度1.067 g/mL at 25 ℃ (lit.)
SMILES stringCC(C)(C)OC(=O)N1CC[C@H](N)C1
InChI1S/C9H18N2O2/c1-9(2,3)13-8(12)11-5-4-7(10)6-11/h7H,4-6,10H2,1-3H3/t7-/m0/s1
InChI keyCMIBWIAICVBURI-ZETCQYMHSA-N

安全信息

象形图GHS05GHS06
警示用语:Danger
危险声明H301 - H318
预防措施声明P280 - P301 + P310 + P330 - P305 + P351 + P338 + P310
危险分类Acute Tox. 3 Oral - Eye Dam. 1
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 2
闪点(F)195.8 °F - closed cup
闪点(C)91 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
011314Fluorochem(S)-3-Amino-1-N-Boc-pyrrolidine98%220元/1g;   462元/5g;   726元/10g;   1540元/25g;   展开

基本信息

CAS Number147081-44-5
MDL NumberMFCD03419271
Boiling Point216-217℃
Density1.067

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H318: Causes serious eye damage.
防范说明 P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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