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CAS: 147-93-3
分子式: C7H6O2S
分子量: 154.19
熔点: 164-169℃
中文名称: 
邻羧基苯硫酚
邻巯基苯甲酸
硫代水杨酸
2-巯基苯甲酸
英文名称: 
2-Mercapto-benzoic acid
o-Mercaptobenzoic acid
2-mercapto-Benzoic acid
Thiosalicylic acid
o-mercapto-benzoic aci
2-carboxythiophenol
2-mercaptobenzoic acid
2-thiosalicylic acid
2-mercapto-benzoic aci
o-benzoic acid thiol
o-mercaptobenzoesaeure
o-sulfhydrylbenzoic acid
o-thiosalicylic acid
2-thio-salicylic aci
usaf ek-t-2805
usaf kf-2
usaf xr-35
Benzoic acid,2-mercapto-
展开更多英文名
性质描述: 黄色叶状(冰乙酸)或针状(乙醇水溶液)结晶。熔点165.5℃,158℃ 软化,能升华,易溶于乙酸,微溶于热水,遇空气得到双硫代水杨酸。
生产方法: 用卤代苯甲酸在铜催化剂存在下与硫氢酸盐反应制得。
用途: 硫柳汞的中间体,也是硫靛蓝色染料中间体,铁测定试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T823200MACKLIN硫代水杨酸98%30元/5g;   54元/25g;   149元/100g;   650元/500g;   3205元/2.5kg;   展开
储存:2~8°C
状态:浅黄色粉末或块状
M0054TCIThiosalicylic Acid>90.0%(T)165元/25G;   1115元/500G;   展开

基本信息

纯度/分析方法>90.0%(T)
分子式/分子量C7H6O2S = 154.18
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN508507
PubChem物质ID87572169
SDBS (AIST Spectral DB)3425
Merck Index (14)9360
MDL编号MFCD00004836

技术规格

AppearanceWhite to Light yellow to Green powder to crystal
Purity(Argentometric Titration)min. 90.0 %

物性(参考值)

熔点167 ℃
溶解性(易溶于)
溶解性(可溶于)乙醚,丙酮

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#DH3325000
393833J&KThiosalicylic Acid98%125元/25G;   410元/100G;   1440元/500G;   展开

基本信息

分子式C7H6O2S
分子量154.19
熔点162-165
MDL编码MFCD00004836
Beilstein508507
Merck14,9360
EINECS 编号205-704-3

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSDH3325000
A13401Alfa AesarThiosalicylic Acid98%753元/50g;   2694元/250g;   6998元/1000g;   展开

应用
Thiosalicylic acid acts as a trapping agent, which is useful in the desulfenylation of 3-indolyl sulfides. It is used to prepare macrocyclic diamides by condensation with diamines. Further, it is used as a precursor to drug, which finds application for the treatment of atherosclerosis and melanoma. In addition to this, it is involved in the preparation of vaccine preservative thiomersal and thioindigo dyestuff.

备注
Air and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00004836

EINECS
205-704-3

分子式
C7H6O2S

分子量
154.19

熔点
165-168°

密度
1.49

灵敏度
Air Sensitive. Light Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in dimethyl sulfoxide, alcohol and ether. Slightly soluble in water, ethanol and alkanes.

Beilstein
508507

Merck
14,9360

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

RTECS
DH3325000

TSCA

C13889Alfa AesarThiosalicylic Acid98%, ACROS OrganicsTM829元/100g;   3336元/500g;   展开

基本信息

Ref#
13889

MDL
MFCD00004836

EINECS
205-704-3

分子式
C7 H6 O2 S

分子量
154.19

熔点
165-168°

密度
1.49

形态
Fine crystalline powder

Beilstein
508507

Merck
14,9360

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

RTECS
DH3325000

TSCA

8.41613Sigma-AldrichThiosalicylic Acidfor synthesis1342.45元/100 G;   展开

产品说明

分析说明

Assay (acidimetric): ≥ 98,0 %(m)
Identity (IR): conforms

基本信息

经验(实验)分子式C7H6O2S
分子量154.19
MDL编号MFCD00004836
EC索引号205-704-3

产品性质

质量水平200
测定≥98.0% (acidimetric)
mp165-166 ℃ (sublimed)
密度1.49 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C7H6O2S/c8-7(9)5-3-1-2-4-6(5)10/h1-4,10H,(H,8,9)
InChI keyNBOMNTLFRHMDEZ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
T33200Sigma-AldrichThiosalicylic Acid97%242.35元/5 G;   1626.71元/100 G;   3475.37元/500 G;   展开

产品说明

应用

Thiosalicylic acid can be used as:

  • A nucleophilic trapping agent for the desulfenylation of 3-indolyl sulfides to obtain 3-unsubstituted indoles.
  • A starting material to prepare 2′-mercaptoacetophenone, which is used in the synthesis of thioflavanone by reacting with lithium diisopropylamide and benzaldehyde.
  • A stabilizing agent in the synthesis of metal nanoparticles.

It can also be used to prepare 2-thioxanthone-thioacetic acid bimolecular system, which is used as a photoinitiator for free radical polymerization.

包装

5, 100, 500 g in poly bottle

基本信息

线性分子式HSC6H4CO2H
分子量154.19
Beilstein508507
EC 号205-704-3
MDL编号MFCD00004836
PubChem化学物质编号24900130
NACRESNA.22

产品性质

质量水平100
测定97%
mp162-165 ℃ (lit.)
SMILES stringOC(=O)c1ccccc1S
InChI1S/C7H6O2S/c8-7(9)5-3-1-2-4-6(5)10/h1-4,10H,(H,8,9)
InChI keyNBOMNTLFRHMDEZ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
051239FluorochemThiosalicylic Acid>90%220元/1g;   308元/25g;   748元/100g;   1650元/250g;   3058元/500g;   展开

基本信息

CAS Number147-93-3
MDL NumberMFCD00004836
Melting Point162-165℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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