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CAS: 147-71-7
分子式: C4H6O6
分子量: 150.09
熔点: 166-170℃
中文名称: 
葡萄酸
二羟基琥珀酸
D-2,3-二羟基琥珀酸
左旋酒石酸
左旋-2,3-二羟基琥珀酸
酒石酸
[S-(R*,R*)]-2,3-二羟基丁二酸
2,3-二羟基丁二酸
D-酒石酸
英文名称: 
d-(-)-tartaric acid
d-tartaric
d-tartaricacid
tartaric acid d-minus
Butanedioic acid,2,3-dihydroxy-,[S-(R*,R*)]-
Butanedioic acid,2,3-dihydroxy-[R-(R*,R*)]-
Tartaric acid
2,3-dihydroxy-, [S-(R*,R*)]-Butanedioic acid
(2S,3S)-(-)-Tartaric acid
2,3-Dihydroxy succinic acid
2,3-dihydroxy-, [s-( theta, theta)]-butanedioic aci
d(-)-tartaric acid (unnatural tartaric acid)
Tartarie acid
展开更多英文名
性质描述: 酒石酸存在三种立体异构体:石旋酒石酸、左旋酒石酸和内消旋酒石酸。等量右旋体和左旋体的混合物的旋光性相互抵消,称为外消旋酒石酸。内消旋体不存在于自然界中,可由化学合成。各种酒石酸都是易溶于水的无色结晶。
生产方法: 酒石酸主要以钾盐的形式存在于多种植物的果实中,也有少量以游离态存在。工业上常用葡萄糖发酵来制取右旋酒石酸;外消旋体可由反丁烯二酸用高锰酸钾氧化制得;内消旋体可顺丁烯二酸用高锰酸钾氧化制得;左旋酒酸可由外消旋体拆分获得。在酒石酸的实际应用领域中,主要使用右旋酒石酸或其复盐,酿制葡萄的副产品酒石是目前实际生产酒石酸的主要原料,所生产的酒石酸都是右旋体。
用途: 酒石酸广泛用作饮料和其他食品的酸化剂,这一用途与柠檬酸类似。酒石酸与单宁合用,可作为酸性染料的媒染剂,也用于照相行业的某些显影和定影操作,其铁盐具有光敏性,因此可用于制作蓝图。酒石酸能与多种金属离子络合,可作金属表面的清洗剂和抛光剂。酒石酸钾钠(罗谢尔盐)可配制费林试剂,还可用于医药作为缓泻剂和利尿剂,还用作辛可芬的中间体。其晶体有压电性质,可用于电子工业。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D819155MACKLIND-(-)-酒石酸99.5%69元/100g;   185元/500g;   660元/2.5kg;   展开
储存:室温
状态:白色到灰白色固体
折射率:-12.5 ° (C=5, H2O)
D819156MACKLIND-(-)-酒石酸试剂级, 99%36元/100g;   123元/500g;   299元/2.5kg;   1456元/12X500g;   展开
储存:室温
状态:白色到几乎白色粉末到晶体
折射率:-12.5 ° (C=5, H2O)
D6071MACKLIND(-)-酒石酸, 2S,3S-二羟基丁二酸>99.0% 生物技术级51元/100g;   136元/500g;   476元/2.5kg;   展开
储存:室温
状态:白色到几乎白色晶体或粉末
折射率:-12.5 ° (C=5, H2O)
T0026TCID-(-)-Tartaric Acid>99.0%(T)170元/25G;   320元/100G;   680元/500G;   展开

基本信息

纯度/分析方法>99.0%(T)
分子式/分子量C4H6O6 = 150.09
外观与形状(20℃)固体
Reaxys-RN1725145
PubChem物质ID87576050
SDBS (AIST Spectral DB)1071
Merck Index (14)9068
MDL编号MFCD00004238

技术规格

AppearanceWhite to Almost white powder to crystal
Optical purity(LC)min. 98.0 ee%
Purity(Neutralization titration)min. 99.0 %
Solubility in Wateralmost transparency

物性(参考值)

比旋光度 [α]D-13° (C=20,H2O)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#WW7875000
122583J&KD-(-)-Tartaric Acid99%60元/25G;   60元/100G;   241元/500G;   展开

基本信息

分子式C4H6O6
分子量150.09
熔点172-174
闪点210
比旋光度([α]20D)-12.8° to -12° (C=20, H2O)
MDL编码MFCD00004238
Beilstein1725145
Merck14,9068
EINECS 编号205-695-6

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
A11264Alfa AesarD-(-)-Tartaric Acid99%403元/25g;   1193元/100g;   5079元/500g;   展开

应用
D-(-)-Tartaric acid is used as a resolving agent in organic synthesis. It is used as a precursor for the preparation of its ester derivatives like D-tartaric acid diethyl ester, D-tartaric acid dimethyl ester and D-tartaric acid diiso-propyl ester. It finds application in the synthesis of chiral aziridine derivative, a common intermediate for the preparation of hydroxyethylamine class HIV protease inhibitors viz. as saquinavir, amprenavir and nelfinavir. It is widely used in the food industry as a beer foaming agent, for food acidity regulations and as a flavoring agent.

备注
Light sensitive. Incompatible with bases, oxidizing agents and reducing agents.

基本信息

MDL
MFCD00004238

EINECS
205-695-6

分子式
C4H6O6

分子量
150.09

熔点
166-170°

闪点
210°(410°F)

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water and alcohol.

Beilstein
1725145

Merck
14,9068

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C13786Alfa AesarD(-)-Tartaric acid99%691元/25g;   1433元/100g;   3257元/250g;   11093元/1kg;   展开

基本信息

Ref#
13786

MDL
4238

分子式
C4 H6 O6

分子量
150.09

闪点
210

T206Sigma-AldrichD-(-)-Tartaric acidReagentPlus®, 99%490.54元/25 G;   733.65元/100 G;   展开

产品说明

一般描述

D-(-)-酒石酸是多晶固体,广泛用作食品添加剂。据报道,它具有压电效应。
D-(−)-酒石酸是多羟基酸。已报道了 d-酒石酸的氧化。通过 X 射线和中子衍射研究了 D-(−)-酒石酸的晶体结构。据报道,酒石酸是大豆脂肪醇的成分之一。酒石酸辅助溶胶-凝胶法生成 Y2O3:Eu3+ 纳米粒子。酒石酸是葡萄和红葡萄酒中的主要酸。

应用

D-(−)-酒石酸可用于合成 HIV-蛋白酶抑制剂奈非那韦。它可用于合成手性氮丙啶衍生物,它是合成沙奎那韦、安普那韦或奈非那韦等羟乙胺类 HIV 蛋白酶抑制剂的常用中间体。
D-(-)-酒石酸已用于填充多晶 D-酒石酸和聚乙烯和硅粉的波导的近场太赫兹时域光谱(THz-TDS)分析。

包装

25, 100 g in poly bottle

其他说明

非天然异构体

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式HO2CCH(OH)CH(OH)CO2H
分子量150.09
Beilstein1725145
EC 号205-695-6
MDL编号MFCD00004238
PubChem化学物质编号24900012
NACRESNA.22

产品性质

质量水平200
描述synthetic
产品线ReagentPlus®
测定99%
旋光性[α]20/D −12°, c = 20 in H2O
光学纯度ee: 99% (GLC)
mp172-174 ℃ (lit.)
溶解性water: soluble 100 mg/mL, clear, colorless
SMILES stringO[C@@H]([C@H](O)C(O)=O)C(O)=O
InChI1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m0/s1
InChI keyFEWJPZIEWOKRBE-LWMBPPNESA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H318
预防措施声明P280 - P305 + P351 + P338 + P310
危险分类Eye Dam. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
95320Sigma-AldrichD-(-)-Tartaric acidpuriss., unnatural form, ≥99.0% (T)277.84元/10 G;   761.06元/50 G;   2573.71元/250 G;   展开

产品说明

一般描述

Tartaric acid is a polyhydroxy acid with wide applications in the textile, pharma, and food industries. It is commonly used as a food additive and acts as an antioxidant and acidification agent. It is also used as a starting material for the preparation of many bioactive molecules.

应用

D-(-)-Tartaric acid may be used in the preparation of enantiospecific homochiral cis-4-formyl β-lactams. It may also be used as a starting material in the synthesis of D-erythro-sphingosine and L-lyxo-phytosphingosine.

其他说明

非天然异构体

基本信息

线性分子式HO2CCH(OH)CH(OH)CO2H
分子量150.09
Beilstein1725145
EC 号205-695-6
MDL编号MFCD00004238
PubChem化学物质编号329770444
NACRESNA.22

产品性质

质量水平200
描述synthetic
等级puriss.
测定≥99.0% (T)
旋光性[α]20/D −13.5±0.5°, c = 10% in H2O
质量unnatural form
灼烧残渣≤0.05%
mp167-171 ℃
172-174 ℃ (lit.)
SMILES stringO[C@@H]([C@H](O)C(O)=O)C(O)=O
InChI1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m0/s1
InChI keyFEWJPZIEWOKRBE-LWMBPPNESA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H318
预防措施声明P280 - P305 + P351 + P338 + P310
危险分类Eye Dam. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
V900613Sigma-AldrichD-(-)-Tartaric acidVetec, reagent grade, 99%387.27元/500 G;   展开

产品说明

包装

500 g in poly bottle

其他说明

非天然异构体

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

线性分子式HO2CCH(OH)CH(OH)CO2H
分子量150.09
Beilstein1725145
EC 号205-695-6
MDL编号MFCD00004238
PubChem化学物质编号329829973

产品性质

等级reagent grade
描述synthetic
产品线Vetec
测定99%
mp172-174 ℃ (lit.)
SMILES stringO[C@@H]([C@H](O)C(O)=O)C(O)=O
InChI1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m0/s1
InChI keyFEWJPZIEWOKRBE-LWMBPPNESA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H318
预防措施声明P280 - P305 + P351 + P338 + P310
危险分类Eye Dam. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
238768AmethystD-(-)-Tartaric Acid99%, 用于合成133元/500G;   展开

基本信息

分子式C4H6O6
分子量150.09
熔点172-174
闪点210
比旋光度([α]20D)-12.5° to -12.0° (C=20 H2O)
MDL编码MFCD00004238
Beilstein1725145
Merck14,9068
EINECS 编号205-695-6

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
044879FluorochemD-(-)-Tartaric Acid98%330元/100g;   1320元/500g;   展开

基本信息

CAS Number147-71-7
MDL NumberMFCD00004238
Melting Point169-171℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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