CAS 146960-90-9; 1,1'-二(二环己基膦)-二茂铁; 1,1'-bis(dicyclohexylphosphino)ferrocene

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货号

品牌

产品名称

规格

包装、参考价格

B803089

MACKLIN

1,1'-二(二环己基膦)-二茂铁

97%

27元/250mg; 31元/1g; 115元/5g; 567元/25g;

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储存：室温
状态：橙色粉末

B5429

TCI

1,1'-Bis(dicyclohexylphosphino)ferrocene

>97.0%(T)(HPLC)

590元/1G; 1990元/5G;

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基本信息

纯度/分析方法	>97.0%(T)(HPLC)
分子式/分子量	C₃₄H₅₂FeP₂ = 578.58
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
Reaxys-RN	17977402
MDL编号	MFCD09038820

技术规格

Appearance	Orange to Brown powder to crystal
Purity(HPLC)	min. 97.0 area%
Purity(Chelometric Titration)	min. 97.0 %
Melting point	129.0 to 133.0 ℃

物性(参考值)

熔点

131 ℃

26-0155

Strem

1,1'-Bis(dicyclohexylphosphino)ferrocene

min. 98%

1185元/500mg; 3495元/2g; 11370元/10g;

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Technical Notes:

1.Ligand for palladium-catalyzed synthesis of oxindoles by amide a-arylation.

2.Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides.

3.Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1 -disubstituted allenes employing alcohols .

4.Ligand for nickel- catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates .

5.Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyI formate to form linear structured phenyl arylpropanoates.

6. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases .

Reference：

1.J. Org. Chem.. 2001, 66, 3402.

2.J.Organometal. Chem.. 2002, 641,

3. J. Am. Chem. Soc., 2011, 133, 1 141.

4.Chem. L ett., 2011, 40, 913.

5.Org. L ett.,2015, 17, 3544.

6. Org. Chem. Front., 2015, 2, 1505.

708933

Sigma-Aldrich

1,1′-Bis(dicyclohexylphosphino)ferrocene

97%

513.78元/250 MG; 1952.36元/1 G;

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基本信息

经验(实验)分子式	C₃₄H₅₂FeP₂
分子量	578.57
MDL编号	MFCD09038820
PubChem化学物质编号	329762837
NACRES	NA.22

产品性质

质量水平	100
测定	97%
形式	powder
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
mp	138 ℃
官能团	phosphine
SMILES string	[Fe].[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
InChI	1S/2C17H26P.Fe/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h27-8,13-16H,1-6,9-12H2;
InChI key	LVWMUECONASIMT-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves