CAS 14694-95-2; 三(三苯基膦)氯化铑(1); Chlorotris(triphenylphosphine)rhodium(I)

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

详情

T799150

MACKLIN

三(三苯基膦)氯化铑(I)

99.9% trace metals basis

398元/250mg; 1100元/1g; 3000元/5g;

展开

储存：室温, 密封

W820522

MACKLIN

三(三苯基膦)氯化铑(I)

97%

192元/200mg; 893元/1g; 4200元/5g;

展开

储存：2~8°C
状态：红棕色到紫色或栗色结晶粉末

T0931

TCI

Tris(triphenylphosphine)rhodium(I) Chloride

>98.0%(T)

1390元/1G;

展开

基本信息

纯度/分析方法	>98.0%(T)
分子式/分子量	C₅₄H₄₅ClP₃Rh = 925.23
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,空气
包装和容器	1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN	14664394
PubChem物质ID	87576749
SDBS (AIST Spectral DB)	5193
Merck Index (14)	9758
MDL编号	MFCD00010016

技术规格

Appearance	Orange to Brown to Dark red powder to crystal
Purity(Argentometric Titration)	min. 98.0 %

物性(参考值)

水溶性	不溶
溶解性(可溶于)	氯仿,二氯甲烷,甲苯,苯
溶解度(极微溶)	甲醇

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

45-0650

Strem

Chlorotris(triphenylphosphine)rhodium(I)

99%

1050元/250mg; 2919元/1g; 11677元/5g;

展开

Technical Notes:

1A homogeneous hyd rogenation catalyst which operates under mild cond itions .

2.Catalyst for the decarbonylation of aldehydes .

3.Catalyst for regio- and stereoselective allylic substitution reactions.

4.Alkyne hydro-phos phorylation

5.Heck-type reaction with a, ß-unsaturated esters.

6.Rh(l)-catalyzed ortho-alkenylation of aromatic ketimines with alkynes

7.Allylic alcohol-olefin cou pling.

8.Terminal alkenes from ketone s .

9.Rh-catalyzed isomerization of a-aryl propargyI alcohols to indanones.

11.Reductive de protection of silyl groups .

Intramolecular carbo-acylation reaction.

12.Rearrangement of 3-iminocyclopropenes.

13.Reductive a acylation of enones to form 1 ,3-diketones.

14Rh-catalyzed C-H activation/cycloisome rization.

15.Rh-catalyzed 2+2+2 cycloaddition.

16. Cross-coupling of alcohols at ß-position with aldehydes.

45-0670

Strem

Polymer-bound chlorotris(triphenylphosphine)rhodium(I) on styrene-divinylbenzene copolymer

20% cross-linked

4425元/1g; 17640元/5g;

展开

Technical Notes:

1. A homogeneous hydrogenation catalyst which operates under mild conditions.

2.Catalyst for the decarbonylation of aldehydes.

3.Catalyst for regio- and stereoselective allylic substitution reactions.

4.Alkyne hydro-phosphorylation

5. Heck-type reaction with a,ß-unsaturated esters.

Rh(l)-catalyzed ortho-alkenylation of aromatic ketimines with alkynes Allylic alcohol-olefin coupling.

References:

1.Progress Inorg. Chem., 1984, 28.

2.J. Org. Chem., 1992, 57, 5075

3.Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 2, 1253.

4.Org. L ett., 1999, 1, 1929.

5.Angew. Chem. Int. Ed., 2001, 40, 1929.

6.Chem. Commun., 2003, 2438.

7.Org. Lett., 2003, 5, 2759 .

8.J. Org. Chem., 2002, 67, 3945.

010468

Alfa Aesar

Chlorotris(triphenylphosphine)rhodium(I)

97%

0元/1g; 0元/5g;

展开

应用
Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes.

备注
Slowly decomposes in air

基本信息

MDL
MFCD00010016

EINECS
238-744-5

分子式
C₅₄H₄₅ClP₃Rh

分子量
925.23

熔点
ca 250° dec.

灵敏度
Keep Cold.

形态
Micro Crystals

溶解性
Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution

Merck
14,10047

GHS危害和防范说明

Hazard Statements
H413
May cause long lasting harmful effects to aquatic life.

安全信息

危险类别
53
May cause long-term adverse effects in the aquatic environment.

安全等级
60-61
This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

TSCA
是

C19457

Alfa Aesar

Tris(triphenylphosphine)rhodium(I) Chloride

99.99%, (trace metal basis)

1002元/250mg; 3998元/1g; 19022元/5g;

展开

基本信息

Ref#
19457

MDL
10016

分子式
C54 H45 Cl P3 Rh

分子量
925.23

C19042

Alfa Aesar

Tris(triphenylphosphine)rhodium(I) Chloride

98%

3998元/1g; 19022元/5g;

展开

基本信息

Ref#
19042

MDL
10016

分子式
C54 H45 Cl P3 Rh

分子量
925.23

形态
Micro Crystals

199982

Sigma-Aldrich

Tris(triphenylphosphine)rhodium(I) Chloride

2194.14元/1 G; 10249.1元/5 G;

展开

产品说明

应用

硅氢化催化剂

用于许多有机反应的催化剂，包括：

化学选择性烯丙基烷基化
Si-H 键的化学计量活化与硅氢化反应
烯烃分子间和分子内加氢酰化(含助催化剂)
二有机硅烷的聚合

包装

1, 5 g in glass bottle

基本信息

线性分子式	[(C₆H₅)₃P]₃RhCl
分子量	925.22
Beilstein	4581440
EC 号	238-744-5
MDL编号	MFCD00010016
PubChem化学物质编号	24851950
NACRES	NA.22

产品性质

质量水平	200
reaction suitability	core: rhodium reagent type: catalyst
SMILES string	Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.ClH.Rh/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h31-15H;1H;/q;;;;+1/p-1
InChI key	IXAYKDDZKIZSPV-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H317 - H413
预防措施声明	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
危险分类	Aquatic Chronic 4 - Skin Sens. 1
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	Eyeshields, Gloves, type N95 (US)

205036

Sigma-Aldrich

Tris(triphenylphosphine)rhodium(I) Chloride

99.9% trace metals basis

489.22元/250 MG; 1786.08元/1 G; 3052.29元/5 G;

展开

产品说明

应用

硅氢化催化剂

用于许多有机反应的催化剂，包括：

化学选择性烯丙基烷基化
Si-H 键的化学计量活化与硅氢化反应
烯烃分子间和分子内加氢酰化(含助催化剂)
二有机硅烷的聚合

用于芳基硼酸与活化的烯基甲苯磺酸酯进行交叉偶联反应的有效催化剂。也用于催化 DABCO 作用下烯丙基酚醚裂解为酚。

包装

250 mg in glass bottle
5 g in poly bottle
1 g in glass bottle

基本信息

线性分子式	[(C₆H₅)₃P]₃RhCl
分子量	925.22
Beilstein	4581440
EC 号	238-744-5
MDL编号	MFCD00010016
PubChem化学物质编号	24852305
NACRES	NA.22

产品性质

质量水平	100
测定	99.9% trace metals basis
reaction suitability	core: rhodium reagent type: catalyst
SMILES string	Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.ClH.Rh/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h31-15H;1H;/q;;;;+1/p-1
InChI key	IXAYKDDZKIZSPV-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H317 - H413
预防措施声明	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
危险分类	Aquatic Chronic 4 - Skin Sens. 1
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	Eyeshields, Gloves, type N95 (US)

048596

Fluorochem

Chlorotris(triphenylphosphine)rhodium(I)

97%

1826元/1g; 9020元/5g;

展开

基本信息

CAS Number	14694-95-2
MDL Number	MFCD00010016

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .